Extra Electronic Outer-Shell Peculiarities Accessible under a Joint XPS and DFT Study | Sciact - CRIS-system of Boreskov Institute of Catalysis

Extra Electronic Outer-Shell Peculiarities Accessible under a Joint XPS and DFT Study Full article

Journal

PCCP: Physical Chemistry Chemical Physics
ISSN: 1463-9076 , E-ISSN: 1463-9084

Output data

Year: 2017, Volume: 19, Number: 24, Pages: 15842-15848 Pages count : 7 DOI: 10.1039/c7cp00900c

Tags

X-RAY-ABSORPTION; ADSORPTION; PHOTOEMISSION; SCATTERING; CO; CHEMISORPTION; MOLECULES; Pt(100); DENSITY; OXYGEN

Authors

Cholach A.R. ¹ , Asanov I.P. ^2,3 , Bryliakova A.A. ¹ , Okotrub A.V. ^2,3

Affiliations

1	Boreskov Institute of Catalysis, Akademik Lavrentiev Ave 5, Novosibirsk 630090, Russian Federation
2	Nikolaev Institute of Inorganic Chemistry, Akademik Lavrentiev Ave 3, Novosibirsk 630090, Russian Federation
3	Novosibirsk State University, Pirogov Str 2, Novosibirsk 630090, Russian Federation

Funding (2)

1	Russian Foundation for Basic Research	16-03-00048
2	Russian Foundation for Basic Research	17-03-00049

Electronic configuration of chemically bound atoms at the surface, including adsorbed species, or in the bulk of a solid contains a set of natural traps for energy absorption provided by valence band transitions or plasmon oscillations. The core level excitation of any origin is generally coupled with those traps, forming a multichannel route for nonradiative energy dissipation. Using an example of Pt and graphite-based materials, the study shows experimental tracing over these channels by means of elastic electron scattering and X-ray photoelectron spectroscopy. As a complement to the experimental data, calculations of the density of states provide information on chemical behavior and local geometry of the atoms in a sample.

Cholach A.R. , Asanov I.P. , Bryliakova A.A. , Okotrub A.V.
Extra Electronic Outer-Shell Peculiarities Accessible under a Joint XPS and DFT Study

PCCP: Physical Chemistry Chemical Physics. 2017. V.19. N24. P.15842-15848. DOI: 10.1039/c7cp00900c WOS Scopus РИНЦ ANCAN PMID OpenAlex

Full text from publisher

Submitted:	Feb 10, 2017
Accepted:	May 22, 2017
Published online:	May 22, 2017
Published print:	Jun 1, 2017

Web of science:	WOS:000403965500024
Scopus:	2-s2.0-85024117302
Elibrary:	31057040
Chemical Abstracts:	2017:823137
Chemical Abstracts (print):	167:295753
PMID:	28585647
OpenAlex:	W2619130422

DB	Citing
Web of science	5
Scopus	5
Elibrary	4
OpenAlex	6