Crystalline Molybdovanadium Compounds of [Se2Mo2V6O28]6-, [MoV9O28]5-, [VMo5O19]3-Anions | Sciact - CRIS-system of Boreskov Institute of Catalysis

Crystalline Molybdovanadium Compounds of [Se2Mo2V6O28]6-, [MoV9O28]5-, [VMo5O19]3-Anions Full article

Journal

Russian Journal of Inorganic Chemistry
ISSN: 0036-0236 , E-ISSN: 1531-8613

Output data

Year: 1989, Volume: 34, Number: 12, Pages: 1767-1770 Pages count : 4

Authors

Derkach L.V. ¹ , Markes-Rios A. ¹ , Maksimovskaya R.I. ² , Muzychenko A.V. ²

Affiliations

1	VI Lenin State University, Kishinev, Moldavia, USSR
2	Institute of Catalysis, Siberian Branch, Academy of Sciences of the USSR

Crystalline compounds of three types: (NH3-CH2-CH2-NH3)2Na2[Se2Mo2V6O28] · 8H2O (1), [(CH3)4N]2Na2NH4[MoV9O28] · 5H2O (2), [(CH3)4N]2NH4[VMo5O19] (3) are isolated in Se4+-Mo6+-V5+-HCl system. For the first type of crystals on the basis of results of chemical analysis a formula of mixed decavanadate including simultaneously selenium(4), molybdenum(6) and vanadium(5) is suggested. Crystals (2), (3) are identified on the basis of chemical analysis, IR and 51V NMR spectra.

Derkach L.V. , Markes-Rios A. , Maksimovskaya R.I. , Muzychenko A.V.
Crystalline Molybdovanadium Compounds of [Se2Mo2V6O28]6-, [MoV9O28]5-, [VMo5O19]3-Anions
Russian Journal of Inorganic Chemistry. 1989. V.34. N12. P.1767-1770. РИНЦ

Деркач Л.В. , Маркес Риос A. , Максимовская Р.И. , Музыченко А.В.
Кристаллические молибдованадиевые соединения анионов [Se2Mo2V6O28]6-, [MoV9O28]5-, [VMo5O19]3-
Журнал неорганической химии. 1989. Т.34. №12. С.3094-3097. WOS РИНЦ ANCAN

Submitted:	Mar 2, 1989
Published print:	Dec 1, 1989

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