Nitrous Oxide as a Selective Oxidant for Ketonization of C=C Double Bonds in Organic Compounds Review
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Russian Chemical Reviews
ISSN: 0036-021X , E-ISSN: 1468-4837 |
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| Output data | Year: 2017, Volume: 86, Number: 6, Pages: 510-529 Pages count : 20 DOI: 10.1070/RCR4697 | ||||
| Tags | LIQUID-PHASE OXIDATION; 1,3-DIPOLAR CYCLOADDITIONS; AMMONIA OXIDATION; Mn/Bi/Al CATALYST; CARBON-MONOXIDE; ALKENES; CHEMISTRY; RUBBER; COPOLYMERIZATION; CARBOXIDATION | ||||
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| Affiliations |
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Funding (1)
| 1 | Federal Agency for Scientific Organizations | 0303-2016-0006 (V.44.1.6) |
Abstract:
The oxidation chemistry of nitrous oxide (N2O) includes a wide range of both catalytic and non-catalytic selective oxidation reactions. This review summarizes the results of modern experimental and theoretical studies devoted to non-catalytic oxidation reactions ofN2Owith carbon ± carbon double bonds of alkenes and polymers. It is shown that these reactions open up a promising way for the synthesis of diverse carbonyl compounds (ketones and aldehydes) as well as a new type of functionalized oligomersDunsaturated polyketones. Possible applications of unsaturated polyketones, as well as economic aspects of N2O production and use as a selective oxidant are discussed.
Cite:
Dubkov K.A.
, Panov G.I.
, Parmon V.N.
Nitrous Oxide as a Selective Oxidant for Ketonization of C=C Double Bonds in Organic Compounds
Russian Chemical Reviews. 2017. V.86. N6. P.510-529. DOI: 10.1070/RCR4697 WOS Scopus РИНЦ РИНЦ AN OpenAlex
Nitrous Oxide as a Selective Oxidant for Ketonization of C=C Double Bonds in Organic Compounds
Russian Chemical Reviews. 2017. V.86. N6. P.510-529. DOI: 10.1070/RCR4697 WOS Scopus РИНЦ РИНЦ AN OpenAlex
Original:
Дубков К.А.
, Панов Г.И.
, Пармон В.Н.
Оксид азота(I) как селективный окислитель в реакциях кетонизации двойных связей C=C органических соединений
Успехи химии. 2017. Т.86. №6. С.510-529. РИНЦ
Оксид азота(I) как селективный окислитель в реакциях кетонизации двойных связей C=C органических соединений
Успехи химии. 2017. Т.86. №6. С.510-529. РИНЦ
Dates:
| Submitted: | Oct 11, 2016 |
| Published online: | Jun 29, 2017 |
| Published print: | Jun 30, 2017 |
Identifiers:
| Web of science: | WOS:000404957500003 |
| Scopus: | 2-s2.0-85021422129 |
| Elibrary: | 29730369 | 32803580 |
| Chemical Abstracts: | 2018:160629 |
| OpenAlex: | W2562520103 |