Nitrogen Doped Carbon Nanotubes and Nanofibers: Composition, Structure, Electrical Conductivity and Capacity Properties | Sciact - CRIS-system of Boreskov Institute of Catalysis

Nitrogen Doped Carbon Nanotubes and Nanofibers: Composition, Structure, Electrical Conductivity and Capacity Properties Full article

Journal

Carbon
ISSN: 0008-6223 , E-ISSN: 1873-3891

Output data

Year: 2017, Volume: 122, Pages: 475-483 Pages count : 9 DOI: 10.1016/j.carbon.2017.06.094

Tags

ENHANCED PHOTOCATALYTIC CAPABILITY; RAY PHOTOELECTRON-SPECTROSCOPY; POWDER DIFFRACTION PATTERNS; RAMAN-SPECTROSCOPY; FORMIC-ACID; ETHYLENE/AMMONIA MIXTURE; ELECTRONIC-PROPERTIES; HYDROGEN-PRODUCTION; LITHIUM STORAGE; VISIBLE-LIGHT

Authors

Podyacheva Olga Yu. ^1,2,3 , Cherepanova Svetlana V. ^1,2 , Romanenko Anatoly I. ⁴ , Kibis Lidiya S. ^1,2 , Svintsitskiy Dmitry A. ^1,2,3 , Boronin Andrei I. ^1,2,3 , Stonkus Olga A. ^1,2 , Suboch Arina N. ^1,2 , Puzynin Andrei V. ^3,5 , Ismagilov Zinfer R. ^1,3

Affiliations

1	Boreskov Institute of Catalysis, SB RAS, Novosibirsk 630090, Russia
2	Novosibirsk State University, Novosibirsk 630090, Russia
3	Institute of Coal Chemistry and Materials Science FRC CCC SB RAS, Kemerovo 650000, Russia
4	Nikolaev Institute of Inorganic Chemistry, SB RAS, Novosibirsk, Russia
5	T.F. Gorbachev Kuzbass State Technical University, Kemerovo 650000, Russia

Funding (1)

Russian Science Foundation

15-13-10043

Structurally different nitrogen doped nanotubes and nanofibers (N-CNTs and N-CNFs) synthesized by a standard method of decomposing ethylene-ammonia mixtures on metal catalysts were studied. In N-CNTs the uniform distribution of nitrogen and the formation of the ordered defects were registered. The ordered defects comprise four carbon vacancies and pyridine-like nitrogen, according to the performed structural simulation. On the contrary, N-CNFs were found to have the non-uniform distribution of nitrogen; their structural defects are disordered and also contain the pyridine-like nitrogen. An increase in the nitrogen content in N-CNTs, and hence in the amount of ordered defects, leads to a monotonic decrease in conductivity. For N-CNFs the dependence of conductivity on the nitrogen content is non-monotonic and is characterized by the extremum due to the competition of electron doping and structure disordering. A similar enhancement of the electrode capacity with raising the nitrogen content both in N-CNTs and N-CNFs was observed and explained by improved hydrophilic properties of the nitrogen doped carbon nanomaterials.

Podyacheva O.Y. , Cherepanova S.V. , Romanenko A.I. , Kibis L.S. , Svintsitskiy D.A. , Boronin A.I. , Stonkus O.A. , Suboch A.N. , Puzynin A.V. , Ismagilov Z.R.
Nitrogen Doped Carbon Nanotubes and Nanofibers: Composition, Structure, Electrical Conductivity and Capacity Properties
Carbon. 2017. V.122. P.475-483. DOI: 10.1016/j.carbon.2017.06.094 WOS Scopus РИНЦ ANCAN OpenAlex

Submitted:	Apr 5, 2017
Accepted:	Jun 27, 2017
Published online:	Jun 29, 2017
Published print:	Oct 1, 2017

Web of science:	WOS:000407394200053
Scopus:	2-s2.0-85021680205
Elibrary:	35482165
Chemical Abstracts:	2017:1128297
Chemical Abstracts (print):	167:254201
OpenAlex:	W2732210808

DB	Citing
Web of science	92
Scopus	95
Elibrary	94
OpenAlex	90