Abstract: CoMoB/Al2O3 catalysts with up to 2 wt.% of B have been synthesized by two different methods an introduction of boron into γ-Al2O3 support during the kneading of the paste or by the impregnating of γ-Al2O3 extrudates by the solution of Mo and Co compounds, citric and boric acids. It is shown that the activity in HDS and HDN of diesel fuel increases with increasing boron content in catalysts. The growth of the activity is associated with the increase in CoMoS phase content, Co dispersity, an average slab length of sulfide active component particles and an average number of slabs per 1000 nm2. The positive effect of boron is much more pronounced for catalysts prepared by the introduction of boron to the solution, since boron is located preferentially on the surface of alumina particles.

Cite: Klimov O.V. , Vatutina Y.V. , Nadeina K.A. , Kazakov M.O. , Gerasimov E.Y. , Prosvirin I.P. , Larina T.V. , Noskov A.S.
CoMoB/Al2O3 Catalysts for Hydrotreating of Diesel Fuel. The Effect of the Way of the Boron Addition to a Support or an Impregnating Solution
Catalysis Today. 2018. V.305. NSI. P.192-202. DOI: 10.1016/j.cattod.2017.07.004 WOS Scopus РИНЦ ANCAN OpenAlex

Dates:

Submitted:	Apr 15, 2017
Accepted:	Jul 4, 2017
Published online:	Jul 5, 2017
Published print:	May 1, 2018

Identifiers:

Web of science:	WOS:000425550100023
Scopus:	2-s2.0-85021865655
Elibrary:	35482193
Chemical Abstracts:	2017:1170392
Chemical Abstracts (print):	168:212417
OpenAlex:	W2733132773

Citing:

DB	Citing
Web of science	19
Scopus	22
Elibrary	23
OpenAlex	25

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