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Synthesis of Carbon Nanofibers by Catalytic CVD of Chlorobenzene over Bulk Nickel Alloy Научная публикация

Журнал Applied Surface Science
ISSN: 0169-4332
Вых. Данные Год: 2018, Том: 427, Страницы: 505-510 Страниц : 6 DOI: 10.1016/j.apsusc.2017.08.227
Ключевые слова Self-disintegration, Bulk nickel alloy, Chlorobenzene, CCVD, RAPET conditions, Ferromagnetic resonance
Авторы Kenzhin Roman M. 1 , Bauman Yuri I. 1 , Volodin Alexander M. 1 , Mishakov Ilya V. 1,2 , Vedyagin Aleksey A. 1,2
Организации
1 Boreskov Institute of Catalysis SB RAS, pr. Ac. Lavrentieva, 5, 630090, Novosibirsk, Russian Federation
2 National Research Tomsk Polytechnic University, Lenin Av., 30, 634050, Tomsk, Russian Federation

Информация о финансировании (1)

1 Российский фонд фундаментальных исследований 16-33-60034

Реферат: Catalytic chemical vapor deposition (CCVD) of chlorobenzene over bulk nickel alloy (nichrome) was studied. The bulk Ni-containing samples being exposed to a contact with aggressive reaction medium undergo self-disintegration followed by growth of carbon nanofibers. This process, also known as a metal dusting, requires the simultaneous presence of chlorine and hydrogen sources in the reaction mixture. Molecule of chlorobenzene complies with these requirements. The experiments on CCVD were performed in a flow-through reactor system. The initial stages of nickel disintegration process were investigated in a closed system under Autogenic Pressure at Elevated Temperature (RAPET) conditions. Scanning and transmission electron microscopies and ferromagnetic resonance spectroscopy were applied to examine the samples after their interaction with chlorobenzene. Introduction of additional hydrogen into the flow-through system was shown to affect the morphology of grown carbon nanofibers.
Библиографическая ссылка: Kenzhin R.M. , Bauman Y.I. , Volodin A.M. , Mishakov I.V. , Vedyagin A.A.
Synthesis of Carbon Nanofibers by Catalytic CVD of Chlorobenzene over Bulk Nickel Alloy
Applied Surface Science. 2018. V.427. P.505-510. DOI: 10.1016/j.apsusc.2017.08.227 WOS Scopus РИНЦ CAPlusCA OpenAlex
Даты:
Поступила в редакцию: 2 июн. 2017 г.
Принята к публикации: 30 авг. 2017 г.
Опубликована online: 6 сент. 2017 г.
Опубликована в печати: 1 янв. 2018 г.
Идентификаторы БД:
Web of science: WOS:000415219100063
Scopus: 2-s2.0-85029041764
РИНЦ: 31124328
Chemical Abstracts: 2017:1491430
Chemical Abstracts (print): 167:422977
OpenAlex: W2752722912
Цитирование в БД:
БД Цитирований
Web of science 8
Scopus 11
РИНЦ 13
OpenAlex 16
Альметрики: