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Synthesis of Secondary Amines by Reductive Amination of Aldehydes with Nitroarenes over Supported Copper Catalysts in a Flow Reactor Научная публикация

Журнал Catalysis Communications
ISSN: 1566-7367 , E-ISSN: 1873-3905
Вых. Данные Год: 2017, Том: 102, Страницы: 108-113 Страниц : 6 DOI: 10.1016/j.catcom.2017.09.001
Ключевые слова Aldehyde, Continuous flow reactor, Molecular hydrogen, Nitroarene, One-pot reductive amination, Supported copper catalyst
Авторы Nuzhdin Alexey L. 1 , Artiukha Ekaterina A. 1 , Bukhtiyarova Galina A. 1 , Derevyannikova Elizaveta A. 1,2 , Bukhtiyarov Valerii I. 1,2
Организации
1 Boreskov Institute of Catalysis SB RAS, Lavrentieva Ave. 5, Novosibirsk 630090, Russia
2 Novosibirsk State University, Pirogova Str. 2, Novosibirsk 630090, Russia

Информация о финансировании (1)

1 Федеральное агентство научных организаций России 0303-2016-0006 (V.44.1.6)

Реферат: Supported copper catalysts were investigated for the one-pot reductive amination of aldehydes with nitroarenes in a continuous flow reactor. This process is considered advantageous compared to current traditional methods, which present several drawbacks, such as toxicity of reducing or alkylation agent, lack of monoalkylation selectivity and large amounts of waste produced. Various secondary amines were synthesized in good to excellent yields in the reactions of aliphatic aldehydes with nitroarenes using molecular hydrogen as a reducing agent. It was found that the yield of secondary amine depends on the rate of formation of intermediate imine.
Библиографическая ссылка: Nuzhdin A.L. , Artiukha E.A. , Bukhtiyarova G.A. , Derevyannikova E.A. , Bukhtiyarov V.I.
Synthesis of Secondary Amines by Reductive Amination of Aldehydes with Nitroarenes over Supported Copper Catalysts in a Flow Reactor
Catalysis Communications. 2017. V.102. P.108-113. DOI: 10.1016/j.catcom.2017.09.001 WOS Scopus РИНЦ CAPlusCA OpenAlex
Даты:
Поступила в редакцию: 20 июн. 2017 г.
Принята к публикации: 3 сент. 2017 г.
Опубликована online: 5 сент. 2017 г.
Опубликована в печати: 1 дек. 2017 г.
Идентификаторы БД:
Web of science: WOS:000413058800025
Scopus: 2-s2.0-85029178266
РИНЦ: 31039549
Chemical Abstracts: 2017:1488910
Chemical Abstracts (print): 167:431173
OpenAlex: W2753150747
Цитирование в БД:
БД Цитирований
Web of science 37
Scopus 39
РИНЦ 32
OpenAlex 38
Альметрики: