Synthesis of Secondary Amines by Reductive Amination of Aldehydes with Nitroarenes over Supported Copper Catalysts in a Flow Reactor | Sciact - CRIS-система Института катализа

Synthesis of Secondary Amines by Reductive Amination of Aldehydes with Nitroarenes over Supported Copper Catalysts in a Flow Reactor Научная публикация

Журнал

Catalysis Communications
ISSN: 1566-7367 , E-ISSN: 1873-3905

Вых. Данные

Год: 2017, Том: 102, Страницы: 108-113 Страниц : 6 DOI: 10.1016/j.catcom.2017.09.001

Ключевые слова

Aldehyde, Continuous flow reactor, Molecular hydrogen, Nitroarene, One-pot reductive amination, Supported copper catalyst

Авторы

Nuzhdin Alexey L. ¹ , Artiukha Ekaterina A. ¹ , Bukhtiyarova Galina A. ¹ , Derevyannikova Elizaveta A. ^1,2 , Bukhtiyarov Valerii I. ^1,2

Организации

1	Boreskov Institute of Catalysis SB RAS, Lavrentieva Ave. 5, Novosibirsk 630090, Russia
2	Novosibirsk State University, Pirogova Str. 2, Novosibirsk 630090, Russia

Информация о финансировании (1)

Федеральное агентство научных организаций России

0303-2016-0006 (V.44.1.6)

Supported copper catalysts were investigated for the one-pot reductive amination of aldehydes with nitroarenes in a continuous flow reactor. This process is considered advantageous compared to current traditional methods, which present several drawbacks, such as toxicity of reducing or alkylation agent, lack of monoalkylation selectivity and large amounts of waste produced. Various secondary amines were synthesized in good to excellent yields in the reactions of aliphatic aldehydes with nitroarenes using molecular hydrogen as a reducing agent. It was found that the yield of secondary amine depends on the rate of formation of intermediate imine.

Nuzhdin A.L. , Artiukha E.A. , Bukhtiyarova G.A. , Derevyannikova E.A. , Bukhtiyarov V.I.
Synthesis of Secondary Amines by Reductive Amination of Aldehydes with Nitroarenes over Supported Copper Catalysts in a Flow Reactor
Catalysis Communications. 2017. V.102. P.108-113. DOI: 10.1016/j.catcom.2017.09.001 WOS Scopus РИНЦ CAPlusCA OpenAlex

Поступила в редакцию:	20 июн. 2017 г.
Принята к публикации:	3 сент. 2017 г.
Опубликована online:	5 сент. 2017 г.
Опубликована в печати:	1 дек. 2017 г.

Web of science:	WOS:000413058800025
Scopus:	2-s2.0-85029178266
РИНЦ:	31039549
Chemical Abstracts:	2017:1488910
Chemical Abstracts (print):	167:431173
OpenAlex:	W2753150747

БД	Цитирований
Web of science	39
Scopus	40
РИНЦ	35
OpenAlex	39