Catalytic Asymmetric Oxygenations with the Environmentally Benign Oxidants H2O2 and O2 Review
| Journal |
Chemical Reviews
ISSN: 0009-2665 , E-ISSN: 1520-6890 |
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| Output data | Year: 2017, Volume: 117, Number: 17, Pages: 11406-11459 Pages count : 53 DOI: 10.1021/acs.chemrev.7b00167 | ||||
| Tags | AQUEOUS HYDROGEN-PEROXIDE; BAEYER-VILLIGER OXIDATION; HIGHLY ENANTIOSELECTIVE EPOXIDATION; JULIA-COLONNA EPOXIDATION; SCHIFF-BASE COMPLEXES; PHASE-TRANSFER CATALYSTS; ELECTRON-DEFICIENT OLEFINS; NONHEME IRON-CATALYSTS; ALPHA,BETA-UNSATURATED CARBONYL-COMPOUNDS; KETOIMINATO MANGANESE(III) COMPLEXES | ||||
| Authors |
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| Affiliations |
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Funding (2)
| 1 | Russian Foundation for Basic Research | 16-29-10666 |
| 2 | Federal Agency for Scientific Organizations | 0303-2016-0005 |
Abstract:
The discovery of simple and efficient catalyst systems for the asymmetric oxofunctionalization of hydrocarbons is a challenging task of catalytic chemistry. In this paper, we give an overview of catalyst systems capable of conducting asymmetric oxygenative transformations of organic molecules and, in line with the major trend to sustainability, relying on green oxidants H2O2 and O2 as the ultimate oxygen source. The full historical period of asymmetric oxidation catalysis (1970 to the present day) is covered; both transition-metal-based and organocatalytic systems are considered. The focus of this review is the catalytic properties of the existing catalyst systems, in particular stereoselectivity, activity, efficiency, and synthetic outlook. At the same time, mechanistic peculiarities of stereoselective oxygen transfer are given attention.
Cite:
Bryliakov K.P.
Catalytic Asymmetric Oxygenations with the Environmentally Benign Oxidants H2O2 and O2
Chemical Reviews. 2017.
V.117. N17. P.11406-11459. DOI: 10.1021/acs.chemrev.7b00167
WOS
Scopus
РИНЦ
ANCAN
PMID
OpenAlex
Catalytic Asymmetric Oxygenations with the Environmentally Benign Oxidants H2O2 and O2
Chemical Reviews. 2017.
V.117. N17. P.11406-11459. DOI: 10.1021/acs.chemrev.7b00167
WOS
Scopus
РИНЦ
ANCAN
PMID
OpenAlex
Files:
Full text from publisher
Dates:
| Submitted: | Mar 23, 2017 |
| Published online: | Aug 17, 2017 |
| Published print: | Sep 13, 2017 |
Identifiers:
| Web of science: | WOS:000411044000006 |
| Scopus: | 2-s2.0-85029370341 |
| Elibrary: | 31047752 |
| Chemical Abstracts: | 2017:1334336 |
| Chemical Abstracts (print): | 167:306495 |
| PMID: | 28816037 |
| OpenAlex: | W2745844311 |