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Pretreatment Effect on the Properties of the Cr–Mg Catalyst for the Gas-Phase Hydrofluorination of Perchloroethylene into Pentafluoroethane Full article

Journal Kinetics and Catalysis
ISSN: 0023-1584 , E-ISSN: 1608-3210
Output data Year: 2017, Volume: 58, Number: 4, Pages: 392-396 Pages count : 5 DOI: 10.1134/S0023158417040164
Tags chromium–magnesium catalyst, gas-phase hydrofluorination, pentafluoroethylene
Authors Petrov R.V. 1 , Zirka A.A. 1 , Reshetnikov S.I. 1
Affiliations
1 Boreskov Institute of Catalysis, Siberian Branch, Russian Academy of Sciences, Novosibirsk, 630090 Russia

Funding (1)

1 Russian Foundation for Basic Research 15-08-04789

Abstract: The effect of the temperature of thermal pretreatment of the precursors of the Cr–Mg catalyst on its physicochemical properties (specific surface area and elemental composition) and catalytic properties has been experimentally investigated. The dehydration of the precursor takes place up to a temperature of ~500°С, making it possible to tune the catalyst composition by varying the heat-treatment temperature. The samples prepared from precursors with various compositions differ in their specific surface area and catalytic activity. The highest activity is shown by the catalyst prepared by heat treatment of the precursor at 330°С.
Cite: Petrov R.V. , Zirka A.A. , Reshetnikov S.I.
Pretreatment Effect on the Properties of the Cr–Mg Catalyst for the Gas-Phase Hydrofluorination of Perchloroethylene into Pentafluoroethane
Kinetics and Catalysis. 2017. V.58. N4. P.392-396. DOI: 10.1134/S0023158417040164 WOS Scopus РИНЦ AN OpenAlex
Original: Петров Р.В. , Зирка А.А. , Решетников С.И.
Влияние предварительной обработки Cr-Mg-катализатора газофазного гидрофторирования перхлорэтилена в пентафторэтан на его свойства
Кинетика и катализ. 2017. Т.58. №4. С.410-414. DOI: 10.7868/S0453881117040177 РИНЦ OpenAlex
Dates:
Submitted: Nov 30, 2016
Published print: Jul 1, 2017
Published online: Aug 2, 2017
Identifiers:
Web of science: WOS:000407057400007
Scopus: 2-s2.0-85026773053
Elibrary: 31080102
Chemical Abstracts: 2017:1262866
OpenAlex: W2741497225
Citing:
DB Citing
Web of science 1
Scopus 1
Elibrary 1
OpenAlex 1
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