Chiral Manganese Aminopyridine Complexes: the Versatile Catalysts of Chemo- and Stereoselective Oxidations with H2O2 | Sciact - CRIS-система Института катализа

Chiral Manganese Aminopyridine Complexes: the Versatile Catalysts of Chemo- and Stereoselective Oxidations with H2O2 Научная публикация

Журнал

Chemical Record
ISSN: 1527-8999 , E-ISSN: 1528-0691

Вых. Данные

Год: 2018, Том: 18, Номер: 1, Страницы: 78-90 Страниц : 13 DOI: 10.1002/tcr.201700032

Ключевые слова

asymmetric epoxidation, C−H oxidation, hydrogen peroxide, manganese, mechanism

Авторы

Ottenbacher Roman V. ^1,2 , Talsi Evgenii P. ^1,2 , Bryliakov Konstantin P. ^1,2

Организации

1	Chemistry Department, Novosibirsk State University, Pirogova 2, Novosibirsk 630090 (Russia)
2	Boreskov Institute of Catalysis, Pr. Lavrentieva 5, Novosibirsk 630090 (Russia)

Информация о финансировании (2)

1	Российский научный фонд	17-13-01117
2	Российский фонд фундаментальных исследований	16-33-00014

In the last decade, manganese(II) complexes with N-donor tetradentate aminopyridine ligands emerged as efficient catalysts of enantioselective epoxidation of olefins and direct selective oxidation of C−H groups in complex organic molecules, with environmentally benign oxidant hydrogen peroxide. In this personal account, we summarize the progress of these catalysts with regard to ligands design, structure-reactivity correlations, evaluation of the substrate scope, as well as mechanistic studies, shedding light on the nature of active sites and the mechanisms of selective oxygenations. Several practically promising catalytic syntheses with the aid of Mn aminopyridine catalysts are exemplified.

Ottenbacher R.V. , Talsi E.P. , Bryliakov K.P.
Chiral Manganese Aminopyridine Complexes: the Versatile Catalysts of Chemo- and Stereoselective Oxidations with H2O2
Chemical Record. 2018. V.18. N1. P.78-90. DOI: 10.1002/tcr.201700032 WOS Scopus РИНЦ CAPlus PMID OpenAlex

Поступила в редакцию:	10 мая 2017 г.
Опубликована online:	14 июл. 2017 г.
Опубликована в печати:	1 янв. 2018 г.

Web of science:	WOS:000419935300007
Scopus:	2-s2.0-85025171244
РИНЦ:	35513224
Chemical Abstracts:	2017:1176039
PMID (PubMed):	28707370
OpenAlex:	W2734658276

БД	Цитирований
Web of science	48
Scopus	51
РИНЦ	43
OpenAlex	51