Chiral Manganese Aminopyridine Complexes: the Versatile Catalysts of Chemo- and Stereoselective Oxidations with H2O2 | Sciact - CRIS-система Института катализа

Chiral Manganese Aminopyridine Complexes: the Versatile Catalysts of Chemo- and Stereoselective Oxidations with H2O2 Научная публикация

Журнал

Chemical Record
ISSN: 1527-8999 , E-ISSN: 1528-0691

Вых. Данные

Год: 2018, Том: 18, Номер: 1, Страницы: 78-90 Страниц : 13 DOI: 10.1002/tcr.201700032

Ключевые слова

asymmetric epoxidation, C−H oxidation, hydrogen peroxide, manganese, mechanism

Авторы

Ottenbacher Roman V. ^1,2 , Talsi Evgenii P. ^1,2 , Bryliakov Konstantin P. ^1,2

Организации

1	Chemistry Department, Novosibirsk State University, Pirogova 2, Novosibirsk 630090 (Russia)
2	Boreskov Institute of Catalysis, Pr. Lavrentieva 5, Novosibirsk 630090 (Russia)

Информация о финансировании (2)

1	Российский научный фонд	17-13-01117
2	Российский фонд фундаментальных исследований	16-33-00014

In the last decade, manganese(II) complexes with N-donor tetradentate aminopyridine ligands emerged as efficient catalysts of enantioselective epoxidation of olefins and direct selective oxidation of C−H groups in complex organic molecules, with environmentally benign oxidant hydrogen peroxide. In this personal account, we summarize the progress of these catalysts with regard to ligands design, structure-reactivity correlations, evaluation of the substrate scope, as well as mechanistic studies, shedding light on the nature of active sites and the mechanisms of selective oxygenations. Several practically promising catalytic syntheses with the aid of Mn aminopyridine catalysts are exemplified.

Ottenbacher R.V. , Talsi E.P. , Bryliakov K.P.
Chiral Manganese Aminopyridine Complexes: the Versatile Catalysts of Chemo- and Stereoselective Oxidations with H2O2
Chemical Record. 2018. V.18. N1. P.78-90. DOI: 10.1002/tcr.201700032 WOS Scopus РИНЦ OpenAlex CAPlus PMID

Поступила в редакцию:	10 мая 2017 г.
Опубликована online:	14 июл. 2017 г.
Опубликована в печати:	1 янв. 2018 г.

≡ Web of science:	WOS:000419935300007
≡ Scopus:	2-s2.0-85025171244
≡ РИНЦ:	35513224
≡ OpenAlex:	W2734658276
≡ Chemical Abstracts:	2017:1176039
≡ PMID (PubMed):	28707370

≡ Web of science	51	Сбор данных от 20.02.2026
≡ Scopus	55	Сбор данных от 22.02.2026
≡ РИНЦ	43	Сбор данных от 22.02.2026
≡ OpenAlex	59	Сбор данных от 22.02.2026