Flow Synthesis of Secondary Amines over Ag/Al2O3 Catalyst by One-Pot reductive Amination of Aldehydes with Nitroarenes Научная публикация
| Журнал |
RSC Advances
ISSN: 2046-2069 |
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| Вых. Данные | Год: 2017, Том: 7, Номер: 72, Страницы: 45856-45861 Страниц : 6 DOI: 10.1039/c7ra08986d | ||||
| Ключевые слова | LIQUID-PHASE HYDROGENATION; CARBONYL-COMPOUNDS; NITRO-COMPOUNDS; Au/Al2O3 CATALYST; RECOVERABLE CATALYST; HIGHLY EFFICIENT; COBALT CATALYST; MILD CONDITIONS; NANOPARTICLES; MONOALKYLATION | ||||
| Авторы |
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| Организации |
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Информация о финансировании (1)
| 1 | Федеральное агентство научных организаций России | 0303-2016-0006 (V.44.1.6) |
Реферат:
An alumina-supported silver catalyst was investigated in the one-pot reductive amination of aldehydes with nitroarenes in a continuous flow reactor using molecular hydrogen as a reducing agent. A series of secondary amines containing alkyl, OH, OCH3, Cl, Br and C[double bond, length as m-dash]C groups was synthesized in good to excellent yields. The yield of the secondary amine depends on the rate of formation of an intermediate imine. It was shown that the accumulation of carbonaceous deposits on the catalyst is the main reason of catalyst deactivation. The spent catalyst can be easily regenerated and reused without losing catalytic activity.
Библиографическая ссылка:
Artyukha E.A.
, Nuzhdin A.L.
, Bukhtiyarova G.A.
, Bukhtiyarov V.I.
Flow Synthesis of Secondary Amines over Ag/Al2O3 Catalyst by One-Pot reductive Amination of Aldehydes with Nitroarenes
RSC Advances. 2017.
V.7. N72. P.45856-45861. DOI: 10.1039/c7ra08986d
WOS
Scopus
РИНЦ
CAPlusCA
OpenAlex
Flow Synthesis of Secondary Amines over Ag/Al2O3 Catalyst by One-Pot reductive Amination of Aldehydes with Nitroarenes
RSC Advances. 2017.
V.7. N72. P.45856-45861. DOI: 10.1039/c7ra08986d
WOS
Scopus
РИНЦ
CAPlusCA
OpenAlex
Файлы:
Полный текст от издателя
Даты:
| Поступила в редакцию: | 14 авг. 2017 г. |
| Принята к публикации: | 20 сент. 2017 г. |
| Опубликована online: | 26 сент. 2017 г. |
Идентификаторы БД:
| Web of science: | WOS:000412147000072 |
| Scopus: | 2-s2.0-85030225688 |
| РИНЦ: | 31051681 |
| Chemical Abstracts: | 2017:1561430 |
| Chemical Abstracts (print): | 167:597913 |
| OpenAlex: | W2758828466 |