Selective Oxidations Catalyzed by Mesoporous Metal Silicates Review
| Source | Liquid Phase Oxidation via Heterogeneous Catalysis: Organic Synthesis and Industrial Applications Monography, John Wiley & Sons, Inc. New Jersey.2013. 546 c. ISBN 9780470915523. WOS Scopus РИНЦ ANCAN |
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| Output data | Year: 2013, Pages: 127-219 Pages count : 93 DOI: 10.1002/9781118356760.ch4 | ||
| Tags | Alkylhydroperoxide, Hydrogen peroxide, Liquid phase oxidation, Mesoporous metal silicate, Mesostructured material, Mixed oxide, Molecular oxygen | ||
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Abstract:
Chapter 4 surveys the progress made in the synthesis of mesoporous transition-metal-containing silicates, both amorphous and well-ordered. The first part describes different strategies for the preparation of such materials as well as their physicochemical characterization. Several approaches elaborated in the last years to create hydrothermally stable mesoporous metal-silicates are in the focus. The second part is devoted to catalytic liquid-phase oxidation processes over mesoporous metal-silicates, with special attention drawn to the structure/activity/selectivity relationships and mechanistic aspects of the oxidation reactions. A special sub-chapter is devoted to the critical analysis of the results published so far in the literature concerning stability of mesoporous metal-silicate catalysts. Deactivation mechanisms are also addressed here. Discussion on the scope and limitations of such materials in liquid-phase oxidations closes the chapter.
Cite:
Kholdeeva O.A.
Selective Oxidations Catalyzed by Mesoporous Metal Silicates
Monography chapter Liquid Phase Oxidation via Heterogeneous Catalysis: Organic Synthesis and Industrial Applications. – John Wiley & Sons, Inc., 2013. – C.127-219. – ISBN 9780470915523. DOI: 10.1002/9781118356760.ch4 WOS Scopus РИНЦ ANCAN OpenAlex
Selective Oxidations Catalyzed by Mesoporous Metal Silicates
Monography chapter Liquid Phase Oxidation via Heterogeneous Catalysis: Organic Synthesis and Industrial Applications. – John Wiley & Sons, Inc., 2013. – C.127-219. – ISBN 9780470915523. DOI: 10.1002/9781118356760.ch4 WOS Scopus РИНЦ ANCAN OpenAlex
Dates:
| Published online: | Apr 26, 2013 |
| Published print: | May 20, 2013 |
Identifiers:
| Web of science: | WOS:000338334100005 |
| Scopus: | 2-s2.0-84886136909 |
| Elibrary: | 21883596 |
| Chemical Abstracts: | 2013:1309909 |
| Chemical Abstracts (print): | 160:515055 |
| OpenAlex: | W1577904372 |