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Transport Features in Layered Nickelates: Correlation between Structure, Oxygen Diffusion, Electrical and Electrochemical Properties Научная публикация

Журнал Ionics
ISSN: 0947-7047 , E-ISSN: 1862-0760
Вых. Данные Год: 2018, Том: 24, Номер: 4, Страницы: 1181-1193 Страниц : 13 DOI: 10.1007/s11581-017-2279-3
Ключевые слова Electrochemical performance, Isotope exchange, Ln2NiO4 + δ, Ruddlesden–Popper phase, SOFC cathode
Авторы Sadykov V.A. 1,2 , Sadovskaya E.M. 1,2 , Pikalova E.Yu. 3,4 , Kolchugin A.A. 3,4 , Filonova E.A. 4 , Pikalov S.M. 5 , Eremeev N.F. 1 , Ishchenko A.V. 1,2 , Lukashevich A.I. 1 , Bassat J.M. 6
Организации
1 Boreskov Institute of Catalysis SB RAS, Novosibirsk 630090, Russia
2 Novosibirsk State University, Novosibirsk 630090, Russia
3 Institute of High Temperature Electrochemistry UB RAS, Yekaterinburg 620137, Russia
4 Ural Federal University, Yekaterinburg 620002, Russia
5 Institute of Metallurgy UB RAS, Yekaterinburg 620016, Russia
6 Institut de Chimie de la Matière Condensée de Bordeaux, 33608 Pessac Cedex, France

Информация о финансировании (3)

1 Российский научный фонд 16-13-00112
2 Российский научный фонд 16-19-00104
3 Министерство образования и науки Российской Федерации 02.A03.21.0006

Реферат: Oxygen migration is increasingly acknowledged as playing an important role in the ionic transport in mixed conductors and influencing the electrode electrochemical performance. The aim of this work was to establish correlations between the structural and electrical properties of undoped (Ln2NiO4 + δ, Ln = La, Pr) and doped (La1.7M0.3NiO4 + δ, M = Ca, Sr, Ba, La0.85Pr0.85Ca0.3NiO4 + δ, Pr1.7Ca0.3NiO4 + δ) layered nickelates and the oxygen diffusion in these materials to determine what influences their electrochemical response. A new technique for temperature programmed isotope exchange of oxides with C18O2 in a flow reactor was applied to investigate oxygen mobility and surface reactivity in the polycrystalline powder samples which provided the means to experimentally demonstrate the appearance of two channels of oxygen migration in the doped materials via cooperative mechanism and via near-dopant position. The electrochemical performance of the electrodes based on the developed materials was found to exhibit a strong dependence on their oxygen transport characteristics.
Библиографическая ссылка: Sadykov V.A. , Sadovskaya E.M. , Pikalova E.Y. , Kolchugin A.A. , Filonova E.A. , Pikalov S.M. , Eremeev N.F. , Ishchenko A.V. , Lukashevich A.I. , Bassat J.M.
Transport Features in Layered Nickelates: Correlation between Structure, Oxygen Diffusion, Electrical and Electrochemical Properties
Ionics. 2018. V.24. N4. P.1181-1193. DOI: 10.1007/s11581-017-2279-3 WOS Scopus РИНЦ CAPlus OpenAlex
Даты:
Поступила в редакцию: 14 июл. 2017 г.
Принята к публикации: 12 сент. 2017 г.
Опубликована online: 24 сент. 2017 г.
Опубликована в печати: 1 апр. 2018 г.
Идентификаторы БД:
Web of science: WOS:000428070800023
Scopus: 2-s2.0-85029769640
РИНЦ: 35483262
Chemical Abstracts: 2017:1549522
OpenAlex: W2760276077
Цитирование в БД:
БД Цитирований
Web of science 35
Scopus 38
РИНЦ 37
OpenAlex 41
Альметрики: