Sciact
  • EN
  • RU

A Study of Pd/SO4/ZrO2/Al2O3 Catalysts in n-Hexane Isomerization Full article

Conference Oil and Gas Engineering : International Scientific Conference
24-28 Apr 2017 , Омск
Journal AIP Conference Proceedings
ISSN: 0094-243X , E-ISSN: 1551-7616
Output data Year: 2017, Volume: 1876, Article number : 020009, Pages count : 7 DOI: 10.1063/1.4998829
Tags PALLADIUM CATALYSTS; PLATINUM; STATE; OXIDE
Authors Dzhikiya O.V. 1 , Smolikov M.D. 1,2 , Kazantsev K.V. 1 , Yablokova S.S. 1 , Kireeva T.V. 1 , Paukshtis E.A. 3 , Gulyaeva T.I. 1 , Belyi A.S. 1,2
Affiliations
1 Institute of Hydrocarbons Processing SB RAS, 54 Neftezavodskaya St, Omsk 644040, Russian Federation
2 Omsk State Technical University, 11 Mira Pr, Omsk 644050, Russian Federation
3 Boreskov Institute of Catalysis SB RAS 5 Lavrentieva Pr, Novosibirsk 630090, Russian Federation

Funding (1)

1 Russian Foundation for Basic Research 16-43-550196

Abstract: The effect of palladium concentration in a range from 0.02 to 1.6 wt.% on characteristics of n-hexane isomerization was studied. The (O2-Hchem) titration and O2 chemisorption study revealed that palladium in Pd/SO4/ZrO2/Al2O3 systems adsorbs hydrogen in a ratio H/Pds = 1.13-1.65 at./at. Investigation of the charge state of the metal by IR spectroscopy of adsorbed CO showed the presence of both the metallic (Pd0) and charged palladium species. Pd/SO4/ZrO2/Al2O3 catalysts with charged palladium atoms exhibit high activity and selectivity in n-hexane isomerization.
Cite: Dzhikiya O.V. , Smolikov M.D. , Kazantsev K.V. , Yablokova S.S. , Kireeva T.V. , Paukshtis E.A. , Gulyaeva T.I. , Belyi A.S.
A Study of Pd/SO4/ZrO2/Al2O3 Catalysts in n-Hexane Isomerization
AIP Conference Proceedings. 2017. V.1876. 020009 :1-7. DOI: 10.1063/1.4998829 WOS Scopus РИНЦ AN OpenAlex
Dates:
Published print: Aug 23, 2017
Published online: Aug 23, 2017
Identifiers:
Web of science: WOS:000410776900009
Scopus: 2-s2.0-85028894254
Elibrary: 31123726
Chemical Abstracts: 2017:1384277
OpenAlex: W2747831608
Citing:
DB Citing
Web of science 1
Scopus 1
Elibrary 1
OpenAlex 2
Altmetrics: