A Study of Pd/SO4/ZrO2/Al2O3 Catalysts in n-Hexane Isomerization Full article
| Conference |
Oil and Gas Engineering : International Scientific Conference 24-28 Apr 2017 , Омск |
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| Journal |
AIP Conference Proceedings
ISSN: 0094-243X , E-ISSN: 1551-7616 |
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| Output data | Year: 2017, Volume: 1876, Article number : 020009, Pages count : 7 DOI: 10.1063/1.4998829 | ||||||
| Tags | PALLADIUM CATALYSTS; PLATINUM; STATE; OXIDE | ||||||
| Authors |
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| Affiliations |
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Funding (1)
| 1 | Russian Foundation for Basic Research | 16-43-550196 |
Abstract:
The effect of palladium concentration in a range from 0.02 to 1.6 wt.% on characteristics of n-hexane isomerization was studied. The (O2-Hchem) titration and O2 chemisorption study revealed that palladium in Pd/SO4/ZrO2/Al2O3 systems adsorbs hydrogen in a ratio H/Pds = 1.13-1.65 at./at. Investigation of the charge state of the metal by IR spectroscopy of adsorbed CO showed the presence of both the metallic (Pd0) and charged palladium species. Pd/SO4/ZrO2/Al2O3 catalysts with charged palladium atoms exhibit high activity and selectivity in n-hexane isomerization.
Cite:
Dzhikiya O.V.
, Smolikov M.D.
, Kazantsev K.V.
, Yablokova S.S.
, Kireeva T.V.
, Paukshtis E.A.
, Gulyaeva T.I.
, Belyi A.S.
A Study of Pd/SO4/ZrO2/Al2O3 Catalysts in n-Hexane Isomerization
AIP Conference Proceedings. 2017. V.1876. 020009 :1-7. DOI: 10.1063/1.4998829 WOS Scopus РИНЦ OpenAlex AN
A Study of Pd/SO4/ZrO2/Al2O3 Catalysts in n-Hexane Isomerization
AIP Conference Proceedings. 2017. V.1876. 020009 :1-7. DOI: 10.1063/1.4998829 WOS Scopus РИНЦ OpenAlex AN
Dates:
| Published print: | Aug 23, 2017 |
| Published online: | Aug 23, 2017 |
Identifiers:
| ≡ Web of science: | WOS:000410776900009 |
| ≡ Scopus: | 2-s2.0-85028894254 |
| ≡ Elibrary: | 31123726 |
| ≡ OpenAlex: | W2747831608 |
| ≡ Chemical Abstracts: | 2017:1384277 |