Steam Reforming of Dimethoxymethane, Methanol and Dimethyl Ether on CuO–ZnO/γ-Al2O3 Catalyst Full article
| Journal |
Kinetics and Catalysis
ISSN: 0023-1584 , E-ISSN: 1608-3210 |
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| Output data | Year: 2017, Volume: 58, Number: 5, Pages: 577-584 Pages count : 8 DOI: 10.1134/S0023158417050196 | ||||
| Tags | copper-zinc catalysts, dimethyl ether, dimetoxymethane, fuel cells, hydrogen, methanol, steam reforming | ||||
| Authors |
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| Affiliations |
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Funding (1)
| 1 | Federal Agency for Scientific Organizations | 0303-2016-0011 |
Abstract:
The performance of a СuO–ZnO/γ-Al2O3 catalyst for the reactions of methanol, dimethyl ether (DME) and dimethoxymethane (DMM) steam reforming (SR) to hydrogen-rich gas was studied. The catalyst was found to be active and selective for methanol and DMM SR producing hydrogen-rich gas with low content of CO (<1 vol %). It provided complete conversion of methanol and DMM at 300°C, and hydrogen productivity of, respectively, 15 and 16.5 . With the use of physicochemical methods and catalytic experiments, it was shown that the catalyst surface contained the acid sites typical for γ-Al2O3, and CuO–ZnO agglomerates, responsible, respectively, for DMM hydration to methanol and formaldehyde, and SR of these compounds to hydrogen-rich gas.
Cite:
Pechenkin A.A.
, Badmaev S.D.
, Belyaev V.D.
, Paukshtis E.A.
, Stonkus O.A.
, Sobyanin V.A.
Steam Reforming of Dimethoxymethane, Methanol and Dimethyl Ether on CuO–ZnO/γ-Al2O3 Catalyst
Kinetics and Catalysis. 2017. V.58. N5. P.577-584. DOI: 10.1134/S0023158417050196 WOS Scopus РИНЦ ANCAN OpenAlex
Steam Reforming of Dimethoxymethane, Methanol and Dimethyl Ether on CuO–ZnO/γ-Al2O3 Catalyst
Kinetics and Catalysis. 2017. V.58. N5. P.577-584. DOI: 10.1134/S0023158417050196 WOS Scopus РИНЦ ANCAN OpenAlex
Original:
Печенкин А.А.
, Бадмаев С.Д.
, Беляев В.Д.
, Паукштис Е.А.
, Стонкус О.А.
, Собянин В.А.
Паровая конверсия диметоксиметана, метанола и диметилового эфира на катализаторе СuO–ZnO/γ-Al2O3
Кинетика и катализ. 2017. Т.58. №5. С.589-597. DOI: 10.7868/S0453881117050227 РИНЦ OpenAlex
Паровая конверсия диметоксиметана, метанола и диметилового эфира на катализаторе СuO–ZnO/γ-Al2O3
Кинетика и катализ. 2017. Т.58. №5. С.589-597. DOI: 10.7868/S0453881117050227 РИНЦ OpenAlex
Dates:
| Submitted: | Dec 12, 2016 |
| Published print: | Sep 1, 2017 |
| Published online: | Sep 30, 2017 |
Identifiers:
| Web of science: | WOS:000411992000011 |
| Scopus: | 2-s2.0-85030649433 |
| Elibrary: | 31076911 |
| Chemical Abstracts: | 2017:1586809 |
| Chemical Abstracts (print): | 170:197092 |
| OpenAlex: | W2760245905 |