The Common Character of the Mechanism of Action of Oxide Polymerization Catalysts | Sciact - CRIS-система Института катализа

The Common Character of the Mechanism of Action of Oxide Polymerization Catalysts Краткое сообщение

Журнал

Kinetics and Catalysis
ISSN: 0023-1584 , E-ISSN: 1608-3210

Вых. Данные

Год: 1969, Том: 10, Номер: 5-2, Страницы: 954-955 Страниц : 2

Ключевые слова

KICAA; TAL

Авторы

Zakharov V.A. ¹ , Kushnareva E.G. ¹ , Ermakov Y.I. ¹

Организации

1	Institute of Catalysis, Academy of Sciences of the USSR

Catalysts based on oxides of metals of variable valency (Cr, Mo, W, or V) have been investigated in the polymerization of ethylene at 75 and 15 atm in benzine solution. Using the method of terminating the polymerization reaction with radioactive alcohol, it was found that such catalysts have an identically polarized active bond, and consequently a common chain growth reaction mechanism. The magnitude of the growth rate constant increases in the series W, Mo, Cr and in the series V, Cr.

Zakharov V.A. , Kushnareva E.G. , Ermakov Y.I.
The Common Character of the Mechanism of Action of Oxide Polymerization Catalysts
Kinetics and Catalysis. 1969. V.10. N5-2. P.954-955. Scopus РИНЦ

Захаров В.А. , Кушнарева Е.Г. , Ермаков Ю.И.
Об общем характере механизма действия окисных катализаторов полимеризации
Кинетика и катализ. 1969. Т.10. №5. С.1164-1165. РИНЦ CAPlusCA

Опубликована в печати:

1 июл. 1969 г.

Scopus:	2-s2.0-0014562817
РИНЦ:	30610348

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