Study of the Mechanisms of the Catalytic Decomposition of Hydrogen Peroxide, by the MO LCAO Method | Sciact - CRIS-система Института катализа

Study of the Mechanisms of the Catalytic Decomposition of Hydrogen Peroxide, by the MO LCAO Method Научная публикация

Журнал

Kinetics and Catalysis
ISSN: 0023-1584 , E-ISSN: 1608-3210

Вых. Данные

Год: 1969, Том: 10, Номер: 6-1, Страницы: 1043-1046 Страниц : 4

Ключевые слова

Catalysis; CHEMICAL REACTIONS, DECOMPOSIT; Hydrogen peroxide; KICAA; PEROXIDE

Авторы

Chernyavskii L.I. ¹ , Sutula V.D. ¹

Организации

1	Institute of Catalysis, Academy of Sciences of the USSR

Two mechanisms for the decomposition of H2O2-the radical- chain and the nonradical mechanisms-have been examined. It has been shown by calculations of the orbital energy along the assumed reaction paths by means of the extended Hueckel method that the radical-chain mechanism is facilitated by the existence of filled catalyst level, situated not lower than the upper half-filled level of the OH. The nonradical mechanism of decomposition, which involves the complex H4O4, according to the results of the calculations, requires the existence of an empty catalyst level and special steric conditions.

Chernyavskii L.I. , Sutula V.D.
Study of the Mechanisms of the Catalytic Decomposition of Hydrogen Peroxide, by the MO LCAO Method
Kinetics and Catalysis. 1969. V.10. N6-1. P.1043-1046. Scopus РИНЦ

Чернявский Л.И. , Сутула В.Д.
Изучение механизмов каталитического разложения перекиси водорода с помощью метода МОЛКАО
Кинетика и катализ. 1969. Т.10. №6. С.1264-1269. РИНЦ CAPlusCA

Опубликована в печати:

1 нояб. 1969 г.

Scopus:	2-s2.0-0014595113
РИНЦ:	30298099

Пока нет цитирований