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Aldose to Ketose Interconversion: Galactose and Arabinose Isomerization over Heterogeneous Catalysts Full article

Journal Catalysis Science and Technology
ISSN: 2044-4753 , E-ISSN: 2044-4761
Output data Year: 2017, Volume: 7, Number: 22, Pages: 5321-5331 Pages count : 11 DOI: 10.1039/c7cy00281e
Tags AL HYDROTALCITE CATALYSTS; CARBON NANOTUBES; BASE CATALYSTS; AQUEOUS-MEDIA; GLUCOSE; FRUCTOSE; WATER; EPIMERIZATION; NANOPARTICLES; DEHYDRATION
Authors Murzin Dmitry Yu. 1 , Murzina Elena V. 1 , Aho Atte 1 , Kazakova Mariya A. 2,3 , Selyutin Alexander G. 2 , Kubicka David 4 , Kuznetsov Vladimir L. 2 , Simakova Irina L. 2
Affiliations
1 Laboratory of Industrial Chemistry and Reaction Engineering, Åbo Akademi University, Biskopsgatan 8, 20500, Turku, Finland. E-mail: dmurzin@abo.fi
2 Boreskov Institute of Catalysis, akad. Lavrentieva 5, Novosibirsk, 630090, Russia
3 Novosibirsk State University, Pirogova 2, Novosibirsk, 630090, Russia
4 Technopark Kralupy of University of Chemistry and Technology Prague, 278 01 Kralupy nad Vltavou, Czech Republic

Funding (3)

1 European Commission 310490 FP7-NMP-2012-SMALL-6 SUSFUELCAT
2 Åbo Akademi University
3 Министерство образования Новосибирской области

Abstract: Isomerization of glucose, galactose and arabinose to corresponding keto-sugars was studied in the present work over a range of heterogeneous catalysts. Magnesium aluminates with different ratios between oxides resulting in materials with a Mg/Al ratio from 0.2 to 0.9 were prepared, characterized and evaluated in terms of their catalytic behavior. The catalyst with a Mg/Al ratio close to hydrotalcites was the most efficient considering activity, selectivity and stability. The sugar structure was shown to have a minor influence on catalytic activity and selectivity.
Cite: Murzin D.Y. , Murzina E.V. , Aho A. , Kazakova M.A. , Selyutin A.G. , Kubicka D. , Kuznetsov V.L. , Simakova I.L.
Aldose to Ketose Interconversion: Galactose and Arabinose Isomerization over Heterogeneous Catalysts
Catalysis Science and Technology. 2017. V.7. N22. P.5321-5331. DOI: 10.1039/c7cy00281e WOS Scopus РИНЦ ANCAN OpenAlex
Files: Full text from publisher
Dates:
Submitted: Feb 14, 2017
Accepted: May 16, 2017
Published online: May 16, 2017
Published print: Nov 21, 2017
Identifiers:
Web of science: WOS:000415063300013
Scopus: 2-s2.0-85034585457
Elibrary: 31054808
Chemical Abstracts: 2017:779992
Chemical Abstracts (print): 167:552563
OpenAlex: W2614229816
Citing:
DB Citing
Web of science 37
Scopus 38
Elibrary 33
OpenAlex 40
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