Aldose to Ketose Interconversion: Galactose and Arabinose Isomerization over Heterogeneous Catalysts | Sciact - CRIS-system of Boreskov Institute of Catalysis

Aldose to Ketose Interconversion: Galactose and Arabinose Isomerization over Heterogeneous Catalysts Full article

Journal

Catalysis Science and Technology
ISSN: 2044-4753 , E-ISSN: 2044-4761

Output data

Year: 2017, Volume: 7, Number: 22, Pages: 5321-5331 Pages count : 11 DOI: 10.1039/c7cy00281e

Tags

AL HYDROTALCITE CATALYSTS; CARBON NANOTUBES; BASE CATALYSTS; AQUEOUS-MEDIA; GLUCOSE; FRUCTOSE; WATER; EPIMERIZATION; NANOPARTICLES; DEHYDRATION

Authors

Murzin Dmitry Yu. ¹ , Murzina Elena V. ¹ , Aho Atte ¹ , Kazakova Mariya A. ^2,3 , Selyutin Alexander G. ² , Kubicka David ⁴ , Kuznetsov Vladimir L. ² , Simakova Irina L. ²

Affiliations

1	Laboratory of Industrial Chemistry and Reaction Engineering, Åbo Akademi University, Biskopsgatan 8, 20500, Turku, Finland. E-mail: dmurzin@abo.fi
2	Boreskov Institute of Catalysis, akad. Lavrentieva 5, Novosibirsk, 630090, Russia
3	Novosibirsk State University, Pirogova 2, Novosibirsk, 630090, Russia
4	Technopark Kralupy of University of Chemistry and Technology Prague, 278 01 Kralupy nad Vltavou, Czech Republic

Funding (3)

1	European Commission	310490 FP7-NMP-2012-SMALL-6 SUSFUELCAT
2	Åbo Akademi University
3	Министерство образования Новосибирской области

Isomerization of glucose, galactose and arabinose to corresponding keto-sugars was studied in the present work over a range of heterogeneous catalysts. Magnesium aluminates with different ratios between oxides resulting in materials with a Mg/Al ratio from 0.2 to 0.9 were prepared, characterized and evaluated in terms of their catalytic behavior. The catalyst with a Mg/Al ratio close to hydrotalcites was the most efficient considering activity, selectivity and stability. The sugar structure was shown to have a minor influence on catalytic activity and selectivity.

Murzin D.Y. , Murzina E.V. , Aho A. , Kazakova M.A. , Selyutin A.G. , Kubicka D. , Kuznetsov V.L. , Simakova I.L.
Aldose to Ketose Interconversion: Galactose and Arabinose Isomerization over Heterogeneous Catalysts

Catalysis Science and Technology. 2017. V.7. N22. P.5321-5331. DOI: 10.1039/c7cy00281e WOS Scopus РИНЦ ANCAN OpenAlex

Full text from publisher

Submitted:	Feb 14, 2017
Accepted:	May 16, 2017
Published online:	May 16, 2017
Published print:	Nov 21, 2017

Web of science:	WOS:000415063300013
Scopus:	2-s2.0-85034585457
Elibrary:	31054808
Chemical Abstracts:	2017:779992
Chemical Abstracts (print):	167:552563
OpenAlex:	W2614229816

DB	Citing
Web of science	38
Scopus	39
Elibrary	33
OpenAlex	41