Synergetic Effect of Ni2P/SiO2 and γ-Al2O3 Physical Mixture in Hydrodeoxygenation of Methyl Palmitate Full article
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Catalysts
ISSN: 2073-4344 |
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| Output data | Year: 2017, Volume: 7, Number: 11, Article number : 329, Pages count : 17 DOI: 10.3390/catal7110329 | ||||
| Tags | Aliphatic esters, Alumina, Biofuel, Hydrodeoxygenation, Nickel phosphide, Synergetic effect | ||||
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| Affiliations |
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Funding (1)
| 1 | Federal Agency for Scientific Organizations | 0303-2016-0012 (V.47.1.4.) |
Abstract:
The Ni2P/SiO2 catalyst, which was prepared by in situ temperature-programmed reduction and in the mixture with the inert (SiC, SiO2) or acidic (γ-Al2O3) material was studied in methyl palmitate hydrodeoxygenation (HDO). Methyl palmitate HDO was carried out at temperatures of 270–330 °C, H2/feed volume ratio of 600 Nm3/m3, and H2 pressure of 3.0 MPa. Ni2P/SiO2 catalyst, diluted with γ-Al2O3 showed a higher activity than Ni2P/SiO2 catalyst diluted with SiC or SiO2. The conversion of methyl palmitate increased significantly in the presence of γ-Al2O3 most probably due to the acceleration of the acid-catalyzed reaction of ester hydrolysis. The synergism of Ni2P/SiO2 and γ-Al2O3 in methyl palmitate HDO can be explained by the cooperation of the metal sites of Ni2P/SiO2 and the acid sites of γ-Al2O3 in consecutive metal-catalyzed and acid-catalyzed reactions of HDO. The obtained results let us conclude that the balancing of metal and acid sites plays an important role in the development of the efficient catalyst for the HDO of fatty acid esters over supported phosphide catalysts.
Cite:
Shamanaev I.V.
, Deliy I.V.
, Gerasimov E.Y.
, Pakharukova V.P.
, Kodenev E.G.
, Aleksandrov P.V.
, Bukhtiyarova G.A.
Synergetic Effect of Ni2P/SiO2 and γ-Al2O3 Physical Mixture in Hydrodeoxygenation of Methyl Palmitate
Catalysts. 2017.
V.7. N11. 329
:1-17. DOI: 10.3390/catal7110329
WOS
Scopus
РИНЦ
ANCAN
OpenAlex
Synergetic Effect of Ni2P/SiO2 and γ-Al2O3 Physical Mixture in Hydrodeoxygenation of Methyl Palmitate
Catalysts. 2017.
V.7. N11. 329
:1-17. DOI: 10.3390/catal7110329
WOS
Scopus
РИНЦ
ANCAN
OpenAlex
Files:
Full text from publisher
Dates:
| Submitted: | Oct 7, 2017 |
| Accepted: | Oct 31, 2017 |
| Published print: | Nov 6, 2017 |
| Published online: | Nov 6, 2017 |
Identifiers:
| Web of science: | WOS:000416780900018 |
| Scopus: | 2-s2.0-85033605548 |
| Elibrary: | 31037196 |
| Chemical Abstracts: | 2018:149782 |
| Chemical Abstracts (print): | 169:223800 |
| OpenAlex: | W2767852752 |