Theoretical Predictions on Dehydrogenation of Methanol over Copper-Silica Catalyst in a Membrane Reactor Full article
| Conference |
13th International Conference on Catalysis in Membrane Reactors 10-13 Jul 2017 , Houston |
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| Journal |
Catalysis Today
ISSN: 0920-5861 , E-ISSN: 1873-4308 |
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| Output data | Year: 2019, Volume: 331, Pages: 35-42 Pages count : 8 DOI: 10.1016/j.cattod.2017.11.023 | ||||
| Tags | Catalytic membrane reactor, Copper-silica catalyst, Mathematical modeling, Methanol dehydrogenation, Methyl formate production | ||||
| Authors |
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| Affiliations |
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Funding (1)
| 1 | Federal Agency for Scientific Organizations | 0303-2016-0014 |
Abstract:
Dehydrogenation of methanol was performed over copper-silica catalyst. Methyl formate decomposition to carbon monoxide and hydrogen was considered as a main side reaction. Tubular and membrane reactors were compared theoretically in terms of efficiency of the process. For this purpose, a two-dimensional non-isothermal stationary mathematical model of the catalytic membrane reactor was developed and applied. The reaction of methanol dehydrogenation (in a tube side) was conjugated with hydrogen oxidation reaction (in a shell side). Conjugation of the processes was found to increase the methanol conversion up to 87% and achieve the methyl formate yield as high as 80% at 125 °C. The impact of various parameters on the process characteristics was studied using the developed mathematical model.
Cite:
Shelepova E.V.
, Ilina L.Y.
, Vedyagin A.A.
Theoretical Predictions on Dehydrogenation of Methanol over Copper-Silica Catalyst in a Membrane Reactor
Catalysis Today. 2019. V.331. P.35-42. DOI: 10.1016/j.cattod.2017.11.023 WOS Scopus РИНЦ РИНЦ ANCAN OpenAlex
Theoretical Predictions on Dehydrogenation of Methanol over Copper-Silica Catalyst in a Membrane Reactor
Catalysis Today. 2019. V.331. P.35-42. DOI: 10.1016/j.cattod.2017.11.023 WOS Scopus РИНЦ РИНЦ ANCAN OpenAlex
Dates:
| Submitted: | May 29, 2017 |
| Accepted: | Nov 19, 2017 |
| Published online: | Nov 21, 2017 |
| Published print: | Jul 1, 2019 |
Identifiers:
| Web of science: | WOS:000465412900007 |
| Scopus: | 2-s2.0-85035086150 |
| Elibrary: | 35480052 | 38605107 |
| Chemical Abstracts: | 2017:1863546 |
| Chemical Abstracts (print): | 170:492327 |
| OpenAlex: | W2770053341 |