The Stability and Evolution of Oil Systems Studied via Advanced Methods in situ Обзор
| Журнал |
Russian Chemical Reviews
ISSN: 0036-021X , E-ISSN: 1468-4837 |
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| Вых. Данные | Год: 2017, Том: 86, Номер: 11, Страницы: 999-1023 Страниц : 25 DOI: 10.1070/RCR4742 | ||||||||
| Ключевые слова | ELECTRON-SPIN-RESONANCE; ANGLE X-RAY; HEAVY CRUDE-OIL; MAGNETIC-RESONANCE; ASPHALTENE AGGREGATION; PARAMAGNETIC-RESONANCE; VANADYL COMPLEXES; MOLECULAR-DYNAMICS; PETROLEUM ASPHALTENES; NMR-SPECTROSCOPY | ||||||||
| Авторы |
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| Организации |
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Информация о финансировании (1)
| 1 | Российский научный фонд | 15-19-00119 |
Реферат:
The potential of physical methods for in situ studies of the phase stability and physicochemical evolution of heavy oils is analyzed. The basic principles of in situ application of the methods are outlined; the scope and limitations of each approach are discussed. Particular attention is paid to the visualization of the asphaltene aggregation process using attenuated total reflection Fourier transform IR spectroscopy and magnetic resonance imaging, as well as small-angle X-ray and neutron scattering, electron spin resonance and electron and optical microscopy. These methods provide complementary information on the properties and behaviour of oil disperse systems on various spatial and temporal scales ranging from the rotational mobility of asphaltene molecules and the dynamics of their local environment with a characteristic time of ∼10–10 s and evolution of the size characteristics and shape of asphaltene aggregates to visualization of asphaltene aggregation and formation of precipitates in crude oils and their blends with spatial resolution from a few to thousands of micrometres with a characteristic time from seconds to hundreds of hours. The approaches described can be efficiently applied in a wide range of temperatures and pressures, as well as in the presence of chemicals that affect the stability of heavy oils.
Библиографическая ссылка:
Martyanov O.N.
, Larichev Y.V.
, Morozov E.V.
, Trukhan S.N.
, Kazarian S.N.
The Stability and Evolution of Oil Systems Studied via Advanced Methods in situ
Russian Chemical Reviews. 2017. V.86. N11. P.999-1023. DOI: 10.1070/RCR4742 WOS Scopus РИНЦ РИНЦ CAPlusCA OpenAlex
The Stability and Evolution of Oil Systems Studied via Advanced Methods in situ
Russian Chemical Reviews. 2017. V.86. N11. P.999-1023. DOI: 10.1070/RCR4742 WOS Scopus РИНЦ РИНЦ CAPlusCA OpenAlex
Оригинальная:
Мартьянов О.Н.
, Ларичев Ю.В.
, Морозов Е.В.
, Трухан С.Н.
, Kazarian S.G.
Развитие и применение современных методов IN SITU для исследования стабильности нефтяных систем и физико-химических процессов в них
Успехи химии. 2017. Т.86. №11. С.999-1023. РИНЦ
Развитие и применение современных методов IN SITU для исследования стабильности нефтяных систем и физико-химических процессов в них
Успехи химии. 2017. Т.86. №11. С.999-1023. РИНЦ
Даты:
| Поступила в редакцию: | 11 апр. 2017 г. |
| Опубликована в печати: | 30 нояб. 2017 г. |
| Опубликована online: | 1 дек. 2017 г. |
Идентификаторы БД:
| Web of science: | WOS:000416805600001 |
| Scopus: | 2-s2.0-85039074143 |
| РИНЦ: | 32274459 | 39130082 |
| Chemical Abstracts: | 2018:766177 |
| Chemical Abstracts (print): | 172:300075 |
| OpenAlex: | W2733233136 |