Halloysite Nanoclay Based CdS Formulations with High Catalytic Activity in Hydrogen Evolution Reaction under Visible Light Irradiation | Sciact - CRIS-system of Boreskov Institute of Catalysis

Halloysite Nanoclay Based CdS Formulations with High Catalytic Activity in Hydrogen Evolution Reaction under Visible Light Irradiation Full article

Journal

ACS Sustainable Chemistry & Engineering
ISSN: 2168-0485

Output data

Year: 2017, Volume: 5, Number: 12, Pages: 11316-11323 Pages count : 8 DOI: 10.1021/acssuschemeng.7b02272

Tags

Cadmium sulfide, Clay, Halloysite nanotubes, Hydrogen, Photocatalysis

Authors

Vinokurov Vladimir ¹ , Stavitskaya Anna V. ¹ , Ivanov Evgenii V. ¹ , Gushchin Pavel A. ¹ , Kozlov Denis V. ^2,3 , Kurenkova Anna Yu. ² , Kolinko Pavel A. ² , Kozlova Ekaterina A. ^2,3 , Lvov Yuri M. ^1,4

Affiliations

1	Department of Physical and Colloid Chemistry, Gubkin Russian State University of Oil and Gas (National Research University), Leninskiy prospect 65/1, Moscow, 119991, Russia
2	Boreskov Institute of Catalysis, Pr. Akademika Lavrentieva, 5, Novosibirsk, 630090, Russia
3	Novosibirsk State University, Pirogova, 2, Novosibirsk, 630090, Russia
4	Institute for Micromanufacturing, Louisiana Tech University, Ruston, Louisiana 71272, United States

Funding (1)

Government of the Russian Federation

14.Z50.31.0035

An efficient and an easily scalable photocatalyst with CdS nanoparticles placed on the outer surface and inside halloysite clay nanotubes with cadmium sulfide content of ca. 3 wt % was developed. The CdS/halloysite core–shell tubule nanocomposites showed a superior catalytic activity and a high stability in the release of hydrogen under visible radiation without cocatalysts or noble metal doping. The specific activity was of 20 mmol of hydrogen per hour per gram of CdS. The suggested approach opens the way to an inexpensive production of highly efficient mesoporous catalyst based on a natural, abundantly available clay support.

Vinokurov V. , Stavitskaya A.V. , Ivanov E.V. , Gushchin P.A. , Kozlov D.V. , Kurenkova A.Y. , Kolinko P.A. , Kozlova E.A. , Lvov Y.M.
Halloysite Nanoclay Based CdS Formulations with High Catalytic Activity in Hydrogen Evolution Reaction under Visible Light Irradiation
ACS Sustainable Chemistry & Engineering. 2017. V.5. N12. P.11316-11323. DOI: 10.1021/acssuschemeng.7b02272 WOS Scopus РИНЦ AN OpenAlex

Submitted:	Jul 7, 2017
Accepted:	Oct 16, 2017
Published online:	Nov 9, 2017
Published print:	Dec 4, 2017

Web of science:	WOS:000417341900020
Scopus:	2-s2.0-85041090513
Elibrary:	35496730
Chemical Abstracts:	2017:1719953
OpenAlex:	W2765971565

DB	Citing
Web of science	81
Scopus	81
Elibrary	82
OpenAlex	89