Template-Assisted Wet-Combustion Synthesis of Fibrous Nickel-Based Catalyst for Carbon Dioxide Methanation and Methane Steam Reforming | Sciact - CRIS-system of Boreskov Institute of Catalysis

Template-Assisted Wet-Combustion Synthesis of Fibrous Nickel-Based Catalyst for Carbon Dioxide Methanation and Methane Steam Reforming Full article

Journal

ACS Applied Materials and Interfaces
ISSN: 1944-8244 , E-ISSN: 1944-8252

Output data

Year: 2017, Volume: 9, Number: 50, Pages: 43553-43562 Pages count : 10 DOI: 10.1021/acsami.7b08129

Tags

carbon dioxide methanation, combustion synthesis, methane steam reforming, nanofibers, Ni-based catalyst

Authors

Aghayan M. ¹ , Potemkin D.I. ^2,3 , Rubio-Marcos F. ⁴ , Uskov S.I. ^2,3 , Snytnikov P.V. ^2,3 , Hussainova I. ^1,5,6

Affiliations

1	Tallinn University of Technology, Ehitajate tee 5, 19086 Tallinn, Estonia
2	Boreskov Institute of Catalysis, Pr. Lavrentieva, 5, Novosibirsk 630090, Russia
3	Novosibirsk State University, Pirogova Street, 2, Novosibirsk 630090, Russia
4	Instituto de Cerámica y Vidrio (ICV-CSIC), C/Kelsen, 5, 28049 Madrid, Spain
5	ITMO University, Kronverkskiy 49, St. Petersburg 197101, Russia
6	University of Illinois at Urbana—Champaign, 1206 West Green Street, Urbana, Illinois 61801, United States

Funding (6)

1	Russian Foundation for Basic Research	16-33-60106
2	Council for Grants of the President of the Russian Federation	СП-922.2016.1
3	Ministry of Economic Affairs and Digital Transformation	MAT2013-48009-C4-1-P
4	Ministry of Economic Affairs and Digital Transformation	RyC-2015-18626
5	Estonian Research Council	PUT1063
6	Фонд Prototron

Efficient capture and recycling of CO2 enable not only prevention of global warming but also the supply of useful low-carbon fuels. The catalytic conversion of CO2 into an organic compound is a promising recycling approach which opens new concepts and opportunities for catalytic and industrial development. Here we report about template-assisted wet-combustion synthesis of a one-dimensional nickel-based catalyst for carbon dioxide methanation and methane steam reforming. Because of a high temperature achieved in a short time during reaction and a large amount of evolved gases, the wet-combustion synthesis yields homogeneously precipitated nanoparticles of NiO with average particle size of 4 nm on alumina nanofibers covered with a NiAl2O4 nanolayer. The as-synthesized core–shell structured fibers exhibit outstanding activity in steam reforming of methane and sufficient activity in carbon dioxide methanation with 100% selectivity toward methane formation. The as-synthesized catalyst shows stable operation under the reaction conditions for at least 50 h.

Aghayan M. , Potemkin D.I. , Rubio-Marcos F. , Uskov S.I. , Snytnikov P.V. , Hussainova I.
Template-Assisted Wet-Combustion Synthesis of Fibrous Nickel-Based Catalyst for Carbon Dioxide Methanation and Methane Steam Reforming
ACS Applied Materials and Interfaces. 2017. V.9. N50. P.43553-43562. DOI: 10.1021/acsami.7b08129 WOS Scopus РИНЦ AN PMID OpenAlex

Submitted:	Jun 7, 2017
Accepted:	Nov 20, 2017
Published online:	Dec 6, 2017
Published print:	Dec 20, 2017

Web of science:	WOS:000418783700017
Scopus:	2-s2.0-85037989132
Elibrary:	35504574
Chemical Abstracts:	2017:1828199
PMID:	29155551
OpenAlex:	W2769204104

DB	Citing
Web of science	30
Scopus	33
Elibrary	30
OpenAlex	32