Internal Field 59 Co NMR Study of Cobalt-Iron Nanoparticles During the Activation of CoFe2/CaO Catalyst for Carbon Nanotube Synthesis | Sciact - CRIS-система Института катализа

Internal Field 59 Co NMR Study of Cobalt-Iron Nanoparticles During the Activation of CoFe2/CaO Catalyst for Carbon Nanotube Synthesis Научная публикация

Журнал

Journal of Catalysis
ISSN: 0021-9517 , E-ISSN: 1090-2694

Вых. Данные

Год: 2018, Том: 358, Страницы: 62-70 Страниц : 9 DOI: 10.1016/j.jcat.2017.11.025

Ключевые слова

59Co NMR, Activation, Catalysts, Cobalt-iron alloy, Induction period, Multi-walled carbon nanotubes

Авторы

Andreev Andrey S. ^1,2 , Krasnikov Dmitry V. ^1,3 , Zaikovskii Vladimir I. ^1,4 , Cherepanova Svetlana V. ^1,4 , Kazakova Mariya A. ^1,4 , Lapina Olga B. ^1,4 , Kuznetsov Vladimir L. ^1,5 , d'Espinose de Lacaillerie Jean–Baptiste ²

Организации

1	Boreskov Institute of Catalysis SB RAS (BIC SB RAS), Novosibirsk, pr. Lavrentieva, 5, 630090, Russia
2	École Supérieure de Physique et de Chimie Industrielles de la Ville de Paris (ESPCI Paris), PSL Research University, Soft Matter Sciences and Engineering Laboratory, CNRS UMR 7615, 10 rue Vauquelin, F-75005 Paris, France
3	Skolkovo Institute of Science and Technology, Nobelya str. 3, Moscow 143025, Russia
4	Novosibirsk State University (NSU), Pirogova str., 2, Novosibirsk 630090, Russia
5	National University of Science and Technology (MISIS), Leninskiy ave. 4, Moscow 119049, Russia

Информация о финансировании (4)

1	Федеральное агентство научных организаций России	0303-2016-0002
2	Российский фонд фундаментальных исследований	17-53-150018
3	Посольство Франции в России
4	Министерство образования и науки Российской Федерации	К3-2017-040

CoFe2/CaO catalysts for multi-walled carbon nanotubes (MWCNT) were characterized during the activation period (T = 670 °C; C2H4/Ar = 1:1, 400 sccm) by internal field 59Co nuclear magnetic resonance. During this induction period, although C2H4 is already reacting, the MWCNT yield remains negligible. The NMR spectra of the catalysts revealed the occurrence of several structural and magnetic species. They were not detectable by conventional X-ray diffraction but the heterogeneity of the metal particles was corroborated by high-resolution transmission electronic microscopy coupled with energy dispersive X-ray spectroscopy. Two samples quenched at different activation time contained, beside non-reacted pure metal Co particles, strong and weak ferromagnetic alloys. During activation, the pure Co metal content dropped and an increase of the ordering of the cobalt-iron alloy in the catalyst was evidenced thus revealing a multistage activation mechanism for the reaction. We propose this ordering process during the induction period to be an intermediate step between the strong ferromagnetic Co rich alloy and the weak ferromagnetic Fe rich one and that it favors the onset of MWCNTs growth.

Andreev A.S. , Krasnikov D.V. , Zaikovskii V.I. , Cherepanova S.V. , Kazakova M.A. , Lapina O.B. , Kuznetsov V.L. , d'Espinose de Lacaillerie J.
Internal Field 59 Co NMR Study of Cobalt-Iron Nanoparticles During the Activation of CoFe2/CaO Catalyst for Carbon Nanotube Synthesis
Journal of Catalysis. 2018. V.358. P.62-70. DOI: 10.1016/j.jcat.2017.11.025 WOS Scopus РИНЦ CAPlusCA OpenAlex

Поступила в редакцию:	8 сент. 2017 г.
Принята к публикации:	22 нояб. 2017 г.
Опубликована online:	12 дек. 2017 г.
Опубликована в печати:	1 февр. 2018 г.

Web of science:	WOS:000424718900008
Scopus:	2-s2.0-85037678185
РИНЦ:	35479971
Chemical Abstracts:	2017:1913712
Chemical Abstracts (print):	169:57603
OpenAlex:	W2773503738

БД	Цитирований
Web of science	29
Scopus	31
РИНЦ	30
OpenAlex	31