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X-Ray Photoelectron and X-Ray Emission Study of the Electronic Structure of Hexanuclear Mn(II,III) Pivalate Complexes Full article

Journal Journal of Structural Chemistry
ISSN: 0022-4766 , E-ISSN: 1573-8779
Output data Year: 2017, Volume: 58, Number: 6, Pages: 1166-1172 Pages count : 7 DOI: 10.1134/S0022476617060142
Tags manganese pivalate with isonicotinamide, XES, XPS
Authors Fedorenko A.D. 1 , Mazalov L.N. 1,2 , Fursova E.Yu. 3 , Ovcharenko V.I. 3 , Kalinkin A.V. 4 , Lavrukhina S.A. 1
Affiliations
1 Nikolaev Institute of Inorganic Chemistry, Siberian Branch, Russian Academy of Sciences, Novosibirsk, Russia
2 Novosibirsk National Research State University, Novosibirsk, Russia
3 International Tomography Center, Siberian Branch, Novosibirsk, Russia
4 Boreskov Institute of Catalysis, Siberian Branch, Novosibirsk, Russia

Abstract: The electronic structure of hexanuclear Mn(II,III) pivalate complexes with tetrahydrofuran and isonicotinamide are studied by X-ray photoelectron spectroscopy and X-ray emission spectroscopy. It is shown that when isonicotinamide substitutes for tetrahydrofuran the spin state of manganese ions is retained; the electron density increases on the manganese and oxygen atoms of the [Mn6(O)2Piv10] core.
Cite: Fedorenko A.D. , Mazalov L.N. , Fursova E.Y. , Ovcharenko V.I. , Kalinkin A.V. , Lavrukhina S.A.
X-Ray Photoelectron and X-Ray Emission Study of the Electronic Structure of Hexanuclear Mn(II,III) Pivalate Complexes
Journal of Structural Chemistry. 2017. V.58. N6. P.1166-1172. DOI: 10.1134/S0022476617060142 WOS Scopus РИНЦ AN OpenAlex
Original: Федоренко А.Д. , Мазалов Л.Н. , Фурсова Е.Ю. , Овчаренко В.И. , Калинкин А.В. , Лаврухина С.А.
Рентгеноэлектронные и рентгеноспектральные исследования электронной структуры комплексов 6-ядерного пивалата Mn(II,III)
Журнал структурной химии. 2017. Т.58. №6. С.1214-1220. DOI: 10.15372/JSC20170614RSCI РИНЦ OpenAlex
Dates:
Submitted: Feb 20, 2017
Published print: Nov 1, 2017
Published online: Nov 26, 2017
Identifiers:
Web of science: WOS:000416232500014
Scopus: 2-s2.0-85036582913
Elibrary: 32259264
Chemical Abstracts: 2017:1866806
OpenAlex: W2769377142
Citing:
DB Citing
Web of science 5
Scopus 6
Elibrary 4
OpenAlex 5
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