Hydrodeoxygenation of Methyl-Substituted Ketones Using the Composite Loading of Hydrogenation and Dehydration Catalysts Full article
| Journal |
Catalysis in Industry
ISSN: 2070-0504 , E-ISSN: 2070-0555 |
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| Output data | Year: 2017, Volume: 9, Number: 4, Pages: 299-307 Pages count : 9 DOI: 10.1134/S2070050417040043 | ||||||
| Tags | 2,4-dimethyl-3-pentanone, composite catalysts loading, dehydration catalysts, high-octane components, hydrodeoxygenation, hydrogenation catalysts, methyl-substituted carbonyl compounds | ||||||
| Authors |
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| Affiliations |
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Funding (2)
| 1 | Federal Agency for Scientific Organizations | 0303-2016-0006 (V.44.1.6) |
| 2 | Gaspromneft-Moscow Oil Refinery |
Abstract:
The hydrogenation/hydrodeoxygenation of methyl-substituted carbonyl compounds to preserve the isomeric structure of a product is one way of controlling its amount of oxygen and improving the chemical stability of motor fuel components. The integration of hydrogenation and dehydration catalysts in one reaction space is an bright example of processes that proceed on these catalysts and positively affect each other. In comparison with the hydrogenation Ni-catalyst, the transformation of 2,4-dimethyl-3-pentanone into 2,4-dimethylpentane over the same catalyst loaded jointly with a zeolite is accompanied by a several-fold increase in hydrogenation rate and operational stability. In the process, the complete hydrodeoxygenation of the parent ketone is observed. Such composite loading can be used to replace bifunctional catalysts.
Cite:
Ivanov D.P.
, Kharitonov A.S.
, Pirutko L.V.
, Noskov A.S.
, Abrashenkov P.A.
, Golovachev V.A.
, Kondrashev D.O.
, Kleimenov A.V.
Hydrodeoxygenation of Methyl-Substituted Ketones Using the Composite Loading of Hydrogenation and Dehydration Catalysts
Catalysis in Industry. 2017. V.9. N4. P.299-307. DOI: 10.1134/S2070050417040043 WOS Scopus РИНЦ OpenAlex
Hydrodeoxygenation of Methyl-Substituted Ketones Using the Composite Loading of Hydrogenation and Dehydration Catalysts
Catalysis in Industry. 2017. V.9. N4. P.299-307. DOI: 10.1134/S2070050417040043 WOS Scopus РИНЦ OpenAlex
Original:
Иванов Д.П.
, Харитонов А.С.
, Пирютко Л.В.
, Носков А.С.
, Абрашенков П.А.
, Головачев В.А.
, Кондрашев Д.О.
, Клейменов А.В.
Гидродеоксигенация метилзамещенных кетонов с использованием композитной загрузки катализатора гидрирования и катализатора дегидратации
Катализ в промышленности. 2017. Т.17. №3. С.210-219. DOI: 10.18412/1816-0387-2017-3-210-219 РИНЦ AN OpenAlex
Гидродеоксигенация метилзамещенных кетонов с использованием композитной загрузки катализатора гидрирования и катализатора дегидратации
Катализ в промышленности. 2017. Т.17. №3. С.210-219. DOI: 10.18412/1816-0387-2017-3-210-219 РИНЦ AN OpenAlex
Dates:
| Submitted: | Feb 13, 2017 |
| Published print: | Oct 1, 2017 |
| Published online: | Dec 16, 2017 |
Identifiers:
| Web of science: | WOS:000423241900003 |
| Scopus: | 2-s2.0-85038225908 |
| Elibrary: | 32259841 |
| OpenAlex: | W2773413243 |