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Synthesis and Characterization of Nanocrystalline M-Mg-O and Carbon-Coated MgO Systems Научная публикация

Конференция 6th International Conference on Material Science and Engineering Technology
20-22 окт. 2017 , Seoul
Сборник Material Science and Engineering Technology VI : Selected papers presented at 6th International Conference on Material Science and Engineering Technology (ICMSET 2017), October 20-22, 2017, Seoul National University, Seoul, Korea
Сборник, 2018. 368 c. ISBN 978-3-0357-1213-1.
Журнал Materials Science Forum
ISSN: 0255-5476 , E-ISSN: 1662-9752
Вых. Данные Год: 2018, Том: 917, Страницы: 157-161 Страниц : 5 DOI: 10.4028/www.scientific.net/MSF.917.157
Ключевые слова Carbon coating, Destructive sorption, Halogenated hydrocarbons, Nanocrystalline magnesium oxide, Sol-gel technique, Two-component oxides
Авторы Karnaukhov Timofey 1,2 , Vedyagin Aleksey 1,3 , Mishakov Ilya 1,3 , Bedilo Alexander 1,4 , Volodin Alexander 1
Организации
1 Boreskov Institute of Catalysis SB RAS, Novosibirsk, 630090, Russian Federation
2 Novosibirsk State University, Novosibirsk, 630090, Russian Federation
3 National Research Tomsk Polytechnic University, Tomsk, 634050, Russian Federation
4 Novosibirsk Institute of Technology, Moscow State University of Design and Technology, Novosibirsk, 630099, Russian Federation

Информация о финансировании (2)

1 Российский научный фонд 16-13-10168
2 Министерство образования и науки Российской Федерации VIU-TOVPM-316/2017

Реферат: Two different approaches to modify the structure and reaction ability of nanocrystalline MgO have been discussed. In the first case, a series of two-component x%MOx–MgO systems (M = Fe, Co and Ni, x = 1–45 wt.%) was synthesized via sol–gel technique. Aqueous solution of inorganic salt precursor was used as a hydrolyzing agent. Samples obtained were characterized by number of physicochemical methods (differential thermal analysis, X-ray diffraction analysis, low-temperature adsorption, etc.). It was shown that presence of inorganic salt in magnesium hydroxide matrix shifts the temperature of decomposition of latter towards lower values. Structural and textural characteristics of MgO-based oxide systems were found to be strongly affected by the presence of additive and their concentration. Formation of joint phase was observed in the case of cobalt oxide only. Second way of MgO modification was represented by creating a controlled carbon coating over its surface via decomposition of C4H10 at 400 °C. The obtained x%C/MgO (x = 1–10 wt.%) samples were shown to possess the improved reaction ability in destruction sorption of CF2Cl2 as well as in catalytic dehydrochlorination of 1-chlorobutane in presence of water vapors.
Библиографическая ссылка: Karnaukhov T. , Vedyagin A. , Mishakov I. , Bedilo A. , Volodin A.
Synthesis and Characterization of Nanocrystalline M-Mg-O and Carbon-Coated MgO Systems
В сборнике Material Science and Engineering Technology VI : Selected papers presented at 6th International Conference on Material Science and Engineering Technology (ICMSET 2017), October 20-22, 2017, Seoul National University, Seoul, Korea. 2018. – C.157-161. – ISBN 978-3-0357-1213-1. DOI: 10.4028/www.scientific.net/MSF.917.157 Scopus РИНЦ OpenAlex
Даты:
Поступила в редакцию: 31 окт. 2017 г.
Принята к публикации: 9 нояб. 2017 г.
Опубликована online: 27 мар. 2018 г.
Идентификаторы БД:
Scopus: 2-s2.0-85045302570
РИНЦ: 35498888
OpenAlex: W2792264513
Цитирование в БД:
БД Цитирований
Scopus 7
РИНЦ 7
OpenAlex 6
Альметрики: