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Calculation of the E.S.R. Spectrum Shape of the Dynamic Biradical System Full article

Journal Molecular Physics
ISSN: 0026-8976 , E-ISSN: 1362-3028
Output data Year: 1974, Volume: 27, Number: 2, Pages: 367-375 Pages count : 9 DOI: 10.1080/00268977400100351
Authors Parmon V.N. 1 , Zhdomirov G.M. 1
Affiliations
1 N. D. Zelinsky Institute of Organic Chemistry, Academy of Sciences U. S. S. R., Leninsky Prospect 47, Moscow B-334, U.S.S.R.

Abstract: The E.S.R. spectrum shape of a dynamic biradical system is calculated by means of the density spin-matrix formalism. The biradical is treated as a system which has two conformations characterized by the different values of the exchange integrals J=J1 and J =J2 and the lifetimes τ2 and τ2 respectively. The influence of both the rate and the strength of exchange interactions on the shape of the spectrum is discussed. Criteria to distinguish the spectra of the cases of both slow and fast exchange are discussed.
Cite: Parmon V.N. , Zhdomirov G.M.
Calculation of the E.S.R. Spectrum Shape of the Dynamic Biradical System
Molecular Physics. 1974. V.27. N2. P.367-375. DOI: 10.1080/00268977400100351 WOS Scopus РИНЦ ANCAN OpenAlex
Dates:
Submitted: Jul 24, 1972
Accepted: May 21, 1973
Published print: Feb 1, 1974
Published online: Aug 22, 2006
Identifiers:
Web of science: WOS:A1974S165100007
Scopus: 2-s2.0-0001364967
Elibrary: 30800367
Chemical Abstracts: 1974:150742
Chemical Abstracts (print): 80:150742
OpenAlex: W2136835963
Citing:
DB Citing
Scopus 49
OpenAlex 51
Web of science 49
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