On the Mechanism of Spin Exchange in Long-Chain Nitroxide Biradicals Full article
| Journal |
Molecular Physics
ISSN: 0026-8976 , E-ISSN: 1362-3028 |
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| Output data | Year: 1975, Volume: 30, Number: 3, Pages: 695-701 Pages count : 7 DOI: 10.1080/00268977500102261 | ||
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Abstract:
It is shown that the E.S.R. spectra of long-chain nitroxide biradicals represent the superposition of the spectrum of the non-reacting radical moieties in the elongated conformation and of that of the cage where the radical moieties are close together and can interact with each other. Inside the cage a fast intramolecular motion is observed. Some thermodynamic parameters of the cage as well as thermodynamic parameters of the motion inside the cage are calculated from the experimental E.S.R. spectra of four biradicals.
Cite:
Parmon V.N.
, Kokorin A.I.
, Zhidomirov G.M.
, Zamaraev K.I.
On the Mechanism of Spin Exchange in Long-Chain Nitroxide Biradicals
Molecular Physics. 1975. V.30. N3. P.695-701. DOI: 10.1080/00268977500102261 WOS Scopus РИНЦ ANCAN OpenAlex
On the Mechanism of Spin Exchange in Long-Chain Nitroxide Biradicals
Molecular Physics. 1975. V.30. N3. P.695-701. DOI: 10.1080/00268977500102261 WOS Scopus РИНЦ ANCAN OpenAlex
Dates:
| Submitted: | Oct 24, 1974 |
| Published print: | Sep 1, 1975 |
| Published online: | Aug 23, 2006 |
Identifiers:
| Web of science: | WOS:A1975AS49400004 |
| Scopus: | 2-s2.0-0009876346 |
| Elibrary: | 30836640 |
| Chemical Abstracts: | 1975:605414 |
| Chemical Abstracts (print): | 83:205414 |
| OpenAlex: | W2153237328 |