Solid-State Hydrogen-Generating Composites Based on Sodium Borohydride: Effect of the Heat Treatment of Boron–Cobalt Catalysts on the Hydrogen Generation Rate Full article
Journal |
Russian Journal of Applied Chemistry
ISSN: 1070-4272 , E-ISSN: 1608-3296 |
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Output data | Year: 2017, Volume: 90, Number: 10, Pages: 1666-1673 Pages count : 8 DOI: 10.1134/s1070427217100160 | ||||||
Tags | RAY PHOTOELECTRON-SPECTROSCOPY; BALL-MILLING PROCESS; ALKALINE NaBH4 SOLUTION; TREATMENT TEMPERATURE; HYDROLYSIS; STORAGE; DECABORANE; PYROLYSIS; STABILITY; BORIDE | ||||||
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Affiliations |
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Funding (1)
1 | Federal Agency for Scientific Organizations | 0303-2016-0015 |
Abstract:
Calcined boron–cobalt catalysts prepared by reduction of cobalt chloride in an aqueous sodium borohydride solution can be successfully used as components of pelletized solid-state hydrogen-generating composites based on sodium borohydride. Morphological changes and phase and chemical transformations occurring in the catalysts with an increase in the calcination temperature were studied. The catalyst performance in hydrolysis of sodium borohydride was determined. The hydrogen generation rate depends on the specific surface area of the calcined sample.
Cite:
Netskina O.V.
, Komova O.V.
, Prosvirin I.P.
, Pochtar’ A.A.
, Ozerova A.M.
, Simagina V.I.
Solid-State Hydrogen-Generating Composites Based on Sodium Borohydride: Effect of the Heat Treatment of Boron–Cobalt Catalysts on the Hydrogen Generation Rate
Russian Journal of Applied Chemistry. 2017. V.90. N10. P.1666-1673. DOI: 10.1134/s1070427217100160 WOS Scopus РИНЦ ANCAN OpenAlex
Solid-State Hydrogen-Generating Composites Based on Sodium Borohydride: Effect of the Heat Treatment of Boron–Cobalt Catalysts on the Hydrogen Generation Rate
Russian Journal of Applied Chemistry. 2017. V.90. N10. P.1666-1673. DOI: 10.1134/s1070427217100160 WOS Scopus РИНЦ ANCAN OpenAlex
Original:
Нецкина О.В.
, Комова О.В.
, Просвирин И.П.
, Почтарь А.А.
, Озерова А.М.
, Симагина В.И.
Твердофазные водородгенерирующие композиции на основе боргидрида натрия: влияние термической обработки бор-кобальтовых катализаторов на скорость генерации водорода
Журнал прикладной химии. 2017. Т.90. №10. С.1351-1358. РИНЦ
Твердофазные водородгенерирующие композиции на основе боргидрида натрия: влияние термической обработки бор-кобальтовых катализаторов на скорость генерации водорода
Журнал прикладной химии. 2017. Т.90. №10. С.1351-1358. РИНЦ
Dates:
Published print: | Oct 1, 2017 |
Submitted: | Oct 24, 2017 |
Published online: | Feb 5, 2018 |
Identifiers:
Web of science: | WOS:000425147900016 |
Scopus: | 2-s2.0-85042072863 |
Elibrary: | 35487725 |
Chemical Abstracts: | 2018:301732 |
Chemical Abstracts (print): | 169:104272 |
OpenAlex: | W2792509436 |