Rice Husk Derived Activated Carbon/Polyaniline Composites As Active Materials For Supercapacitors Full article
Journal |
International Journal of Electrochemcal Science
ISSN: 1452-3981 |
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Output data | Year: 2018, Volume: 13, Pages: 3674-3690 Pages count : 17 DOI: 10.20964/2018.04.34 | ||||
Tags | Activated carbon, Composite materials, Polyaniline, Rice Husk, Synergetic effect | ||||
Authors |
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Affiliations |
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Funding (1)
1 | Russian Foundation for Basic Research | 17-43-540794 |
Abstract:
Composite materials (CM) “carbon/polyaniline” were synthesized using porous activated carbon (AC) produced from carbonized rice husk, which has specific surface area 2265 m2g-1 measured by direct BET method . The series of the CM was synthesized by oxidative aniline polymerization method in the presence of the AC in acidic medium; polyaniline (PAni) content was varied from 18 to 60 wt. %. Electrochemical and properties of the CM were investigated by cyclic voltammetry, galvanostatic charge/discharge and stability tests. Results indicate that properties of the composites are governed by ratio of the components: a form of cyclic voltammogram curves and location of specific ox-red polyaniline peaks strongly depend on the PAni amount. Gravimetric capacitance grows with polymer content in the material and reaches maxima 465 F·g-1 in 1M H2SO4 at discharge current density 0.2 А·g-1 for the sample with polyaniline content 60 wt %. However, durability tests show that the most stable is the sample with the lowest (18 wt. %) polyaniline amount.
Cite:
Lebedeva M.V.
, Ayupov A.B.
, Yeletsky P.M.
, Parmon V.N.
Rice Husk Derived Activated Carbon/Polyaniline Composites As Active Materials For Supercapacitors
International Journal of Electrochemcal Science. 2018.
V.13. P.3674-3690. DOI: 10.20964/2018.04.34
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Rice Husk Derived Activated Carbon/Polyaniline Composites As Active Materials For Supercapacitors
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Dates:
Submitted: | Oct 20, 2017 |
Accepted: | Jan 30, 2018 |
Published online: | Mar 6, 2018 |
Published print: | Apr 1, 2018 |
Identifiers:
Web of science: | WOS:000430452300042 |
Scopus: | 2-s2.0-85045025119 |
Elibrary: | 35518165 |
Chemical Abstracts: | 2018:1728561 |
OpenAlex: | W2791018126 |