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Fast Hydrogen Generation from Solid NH3 BH3 under Moderate Heating and Supplying a Limited Quantity of CoCl2 or NiCl2 Solution Full article

Journal Renewable Energy
ISSN: 0960-1481 , E-ISSN: 1879-0682
Output data Year: 2018, Volume: 121, Pages: 722-729 Pages count : 8 DOI: 10.1016/j.renene.2018.01.089
Tags Ammonia borane Hydrolysis Thermolysis Hydrothermolysis Hydrogen production Catalyst
Authors Gorlova A.M. 1,2 , Kayl N.L. 1,2 , Komova O.V. 1 , Netskina O.V. 1,2 , Ozerova A.M. 1 , Odegova G.V. 1 , Bulavchenko O.A. 1,2 , Ishchenko A.V. 1,2 , Simagina V.I. 1,3
Affiliations
1 Boreskov Institute of Catalysis, Pr. Akademika Lavrentieva 5, Novosibirsk 630090, Russia
2 Novosibirsk State University, Pirogova Str. 2, Novosibirsk 630090, Russia
3 Siberian Branch of the Russian Presidential Academy of National Economy and Public Administration, Nizhegorodskaya 6, Novosibirsk 630102, Russia

Funding (1)

1 Federal Agency for Scientific Organizations 0303-2016-0015

Abstract: New results of an investigation of NH3BH3 dehydrogenation with supplying a limited quantity of aqueous solution of a catalyst precursor to a solid-state bed of the hydride particles with subsequent external heating at 40e90 C are presented. Measurements of the reaction layer temperature and the amount of the evolved hydrogen have shown that at external heating temperature higher than 85С there was acceleration of the first stage of the process, the highly exothermic catalytic hydrolysis of a portion of ammonia borane, which resulted in a stronger heating of the reaction layer and the start of NH3BH3 thermolysis. This type of process is referred to as hydrothermolysis. A TEM, ATR FTIR, and XRD investigation has shown that in the reaction medium the metal chlorides become reduced to an amorphous catalytically active phase. During this process, ammonia reacts with chlorides to form NH4Cl. All of this leads to increased rate of hydrogen generation and hydrogen yield. Gravimetric hydrogen capacity of 7.6 wt% and the average rate of H2 evolution of 39 ml g-1 comp. min-1 have been achieved at molar ratios of NH3BH3/MCl2 = 50 (M = Co, Ni) and H2O/NH3BH3 = 2 and at external heating of 85oС.
Cite: Gorlova A.M. , Kayl N.L. , Komova O.V. , Netskina O.V. , Ozerova A.M. , Odegova G.V. , Bulavchenko O.A. , Ishchenko A.V. , Simagina V.I.
Fast Hydrogen Generation from Solid NH3 BH3 under Moderate Heating and Supplying a Limited Quantity of CoCl2 or NiCl2 Solution
Renewable Energy. 2018. V.121. P.722-729. DOI: 10.1016/j.renene.2018.01.089 WOS Scopus РИНЦ ANCAN OpenAlex
Dates:
Submitted: Sep 11, 2017
Accepted: Jan 22, 2018
Published online: Feb 28, 2018
Published print: Jun 1, 2018
Identifiers:
Web of science: WOS:000426413600066
Scopus: 2-s2.0-85042781807
Elibrary: 35506421
Chemical Abstracts: 2018:218569
Chemical Abstracts (print): 171:241261
OpenAlex: W2790600428
Citing:
DB Citing
Web of science 19
Scopus 20
Elibrary 16
OpenAlex 20
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