Gas-Phase Carbonylation of Dimethoxymethane to Methyl Methoxyacetate on Solid Acids: The Effect of Acidity on the Catalytic Activity Full article
| Journal |
Kinetics and Catalysis
ISSN: 0023-1584 , E-ISSN: 1608-3210 |
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| Output data | Year: 2018, Volume: 59, Number: 1, Pages: 99-103 Pages count : 5 DOI: 10.1134/s0023158418010020 | ||||
| Tags | Brønsted–Evans–Polanyi–Semenov correlations, carbonylation, dimethoxymethane, dimethyl ether, disproportionation, methyl formate, methyl methoxyacetate, methylal, solid acids | ||||
| Authors |
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| Affiliations |
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Funding (1)
| 1 | Federal Agency for Scientific Organizations | 0303-2016-0011 |
Abstract:
The gas-phase carbonylation reaction of dimethoxymethane (DMM) to methyl methoxyacetate on different solid acids was studied. It was established that this reaction was accompanied by the occurrence of a side reaction of DMM disproportionation into dimethyl ether and methyl formate. It was shown that the activity of solid acids in both of the reactions depends on the strength of Brønsted acid sites according to an equation like the Brønsted–Evans–Polanyi–Semenov correlations.
Cite:
Badmaev S.D.
, Smorygina A.S.
, Paukshtis E.A.
, Belyaev V.D.
, Sobyanin V.A.
, Parmon V.N.
Gas-Phase Carbonylation of Dimethoxymethane to Methyl Methoxyacetate on Solid Acids: The Effect of Acidity on the Catalytic Activity
Kinetics and Catalysis. 2018. V.59. N1. P.99-103. DOI: 10.1134/s0023158418010020 WOS Scopus РИНЦ AN OpenAlex
Gas-Phase Carbonylation of Dimethoxymethane to Methyl Methoxyacetate on Solid Acids: The Effect of Acidity on the Catalytic Activity
Kinetics and Catalysis. 2018. V.59. N1. P.99-103. DOI: 10.1134/s0023158418010020 WOS Scopus РИНЦ AN OpenAlex
Original:
Бадмаев С.Д.
, Сморыгина А.С.
, Паукштис Е.А.
, Беляев В.Д.
, Собянин В.А.
, Пармон В.Н.
Газофазное карбонилирование диметоксиметана в метилметоксиацетат на твердых кислотах: влияние кислотности на каталитическую активность
Кинетика и катализ. 2018. Т.59. №1. С.122-126. DOI: 10.7868/S0453881118010124 РИНЦ OpenAlex
Газофазное карбонилирование диметоксиметана в метилметоксиацетат на твердых кислотах: влияние кислотности на каталитическую активность
Кинетика и катализ. 2018. Т.59. №1. С.122-126. DOI: 10.7868/S0453881118010124 РИНЦ OpenAlex
Dates:
| Submitted: | May 21, 2017 |
| Published print: | Jan 1, 2018 |
| Published online: | Mar 6, 2018 |
Identifiers:
| Web of science: | WOS:000426796900010 |
| Scopus: | 2-s2.0-85043296264 |
| Elibrary: | 35537199 |
| Chemical Abstracts: | 2018:384900 |
| OpenAlex: | W2792661612 |