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The Dynamics of Asphaltene Aggregates in Heavy Crude Oils on a Nanometer Scale Studied via Small-Angle X-ray Scattering in Situ Full article

Journal Journal of Petroleum Science and Engineering
ISSN: 0920-4105
Output data Year: 2018, Volume: 165, Pages: 575-580 Pages count : 6 DOI: 10.1016/j.petrol.2018.02.063
Tags Asphaltenes; Heavy crude oils; Aggregation; In-situ; SAXS
Authors Larichev Y.V. 1,2 , Martyanov O.N. 1,2
Affiliations
1 Boreskov Institute of Catalysis, 5 Academican Lavrentiev Avenue, 630090, Novosibirsk, Russia
2 Novosibirsk State University, 2 Pirogov Street, 630090, Novosibirsk, Russia

Funding (1)

1 Russian Science Foundation 15-19-00119

Abstract: This work presents the results of the in situ SAXS study of the asphaltene aggregate transformations due to dilution of several heavy crude oils by heptane within the time range from 5 min to 3 days. The main growth of the asphaltene aggregates was usually observed within first minutes. The analysis of the SAXS data obtained in situ for the oils having significantly different relative content of resins showed their great influence on the dynamics of aggregates formation on a nanometer scale. In particular, it has been shown that the resins can prevent the asphaltene aggregation via certain mechanism which usually leads to the high anisotropy of the aggregates. Therefore the relative content of resin and asphaltenes as well as aromatics and aliphatics lead to the asphaltene aggregates with different shapes and different density of deposits.
Cite: Larichev Y.V. , Martyanov O.N.
The Dynamics of Asphaltene Aggregates in Heavy Crude Oils on a Nanometer Scale Studied via Small-Angle X-ray Scattering in Situ
Journal of Petroleum Science and Engineering. 2018. V.165. P.575-580. DOI: 10.1016/j.petrol.2018.02.063 WOS Scopus РИНЦ AN OpenAlex
Dates:
Submitted: Aug 29, 2017
Accepted: Feb 27, 2018
Published online: Mar 1, 2018
Published print: Jun 1, 2018
Identifiers:
Web of science: WOS:000429896600052
Scopus: 2-s2.0-85042947592
Elibrary: 35519917
Chemical Abstracts: 2018:417125
OpenAlex: W2790004938
Citing:
DB Citing
Web of science 8
Scopus 10
Elibrary 13
OpenAlex 8
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