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Enhancement of the Sorption Ability of Aluminum Oxide Desiccants by Alkaline Modification Научная публикация

Журнал Russian Journal of Applied Chemistry
ISSN: 1070-4272 , E-ISSN: 1608-3296
Вых. Данные Год: 2017, Том: 90, Номер: 11, Страницы: 1810-1818 Страниц : 9 DOI: 10.1134/S1070427217110131
Ключевые слова ACID-BASE PROPERTIES; ADSORPTION
Авторы Isupova L.A. 1 , Danilova I.G. 1 , Danilevich V.V. 1 , Ushakov V.A. 1
Организации
1 Boreskov Institute of Catalysis, Siberian Branch, Russian Academy of Sciences, Novosibirsk, Russia

Информация о финансировании (1)

1 Федеральное агентство научных организаций России 0303-2016-0004

Реферат: The influence of impregnation of aluminum oxide desiccants prepared by centrifugal thermal activation of hydrargillite with alkali (KОН and NaOH) and carbonate (Na2CO3 and K2СО3) solutions on the physicochemical properties of the products was studied. Impregnation with alkali solutions increases the dynamic capacity of the desiccants by a factor of 2 and more, whereas impregnation with carbonate solutions decreases the sorption characteristics of the desiccants at similar texture characteristics. Introduction of alkaline modifiers leads to a considerable decrease in the concentration of Lewis acid sites on the surface and to an increase in the concentration of strong base sites. Linear correlation was revealed between the concentration of strong base sites on the surface of the desiccants and their dynamic capacity in drying of humid air. The desiccants modified by impregnation exhibit not only high static and dynamic capacity, allowing improvement of the drying efficiency, but also considerably enhanced mechanical strength.
Библиографическая ссылка: Isupova L.A. , Danilova I.G. , Danilevich V.V. , Ushakov V.A.
Enhancement of the Sorption Ability of Aluminum Oxide Desiccants by Alkaline Modification
Russian Journal of Applied Chemistry. 2017. V.90. N11. P.1810-1818. DOI: 10.1134/S1070427217110131 WOS Scopus РИНЦ CAPlusCA OpenAlex
Оригинальная: Исупова Л.А. , Данилова И.Г. , Данилевич В.В. , Ушаков В.А.
Повышение эффективности алюмооксидных осушителей путем щелочного модифицирования
Журнал прикладной химии. 2017. Т.90. №11. С.1504-1512. РИНЦ
Даты:
Поступила в редакцию: 31 окт. 2017 г.
Опубликована в печати: 1 нояб. 2017 г.
Опубликована online: 7 мар. 2018 г.
Идентификаторы БД:
Web of science: WOS:000426945200013
Scopus: 2-s2.0-85043383571
РИНЦ: 35544604
Chemical Abstracts: 2018:416811
Chemical Abstracts (print): 168:319443
OpenAlex: W2790152565
Цитирование в БД:
БД Цитирований
Web of science 5
Scopus 5
РИНЦ 5
OpenAlex 8
Альметрики: