Enhancement of the Sorption Ability of Aluminum Oxide Desiccants by Alkaline Modification Научная публикация
Журнал |
Russian Journal of Applied Chemistry
ISSN: 1070-4272 , E-ISSN: 1608-3296 |
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Вых. Данные | Год: 2017, Том: 90, Номер: 11, Страницы: 1810-1818 Страниц : 9 DOI: 10.1134/S1070427217110131 | ||
Ключевые слова | ACID-BASE PROPERTIES; ADSORPTION | ||
Авторы |
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Организации |
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Информация о финансировании (1)
1 | Федеральное агентство научных организаций России | 0303-2016-0004 |
Реферат:
The influence of impregnation of aluminum oxide desiccants prepared by centrifugal thermal activation of hydrargillite with alkali (KОН and NaOH) and carbonate (Na2CO3 and K2СО3) solutions on the physicochemical properties of the products was studied. Impregnation with alkali solutions increases the dynamic capacity of the desiccants by a factor of 2 and more, whereas impregnation with carbonate solutions decreases the sorption characteristics of the desiccants at similar texture characteristics. Introduction of alkaline modifiers leads to a considerable decrease in the concentration of Lewis acid sites on the surface and to an increase in the concentration of strong base sites. Linear correlation was revealed between the concentration of strong base sites on the surface of the desiccants and their dynamic capacity in drying of humid air. The desiccants modified by impregnation exhibit not only high static and dynamic capacity, allowing improvement of the drying efficiency, but also considerably enhanced mechanical strength.
Библиографическая ссылка:
Isupova L.A.
, Danilova I.G.
, Danilevich V.V.
, Ushakov V.A.
Enhancement of the Sorption Ability of Aluminum Oxide Desiccants by Alkaline Modification
Russian Journal of Applied Chemistry. 2017. V.90. N11. P.1810-1818. DOI: 10.1134/S1070427217110131 WOS Scopus РИНЦ CAPlusCA OpenAlex
Enhancement of the Sorption Ability of Aluminum Oxide Desiccants by Alkaline Modification
Russian Journal of Applied Chemistry. 2017. V.90. N11. P.1810-1818. DOI: 10.1134/S1070427217110131 WOS Scopus РИНЦ CAPlusCA OpenAlex
Оригинальная:
Исупова Л.А.
, Данилова И.Г.
, Данилевич В.В.
, Ушаков В.А.
Повышение эффективности алюмооксидных осушителей путем щелочного модифицирования
Журнал прикладной химии. 2017. Т.90. №11. С.1504-1512. РИНЦ
Повышение эффективности алюмооксидных осушителей путем щелочного модифицирования
Журнал прикладной химии. 2017. Т.90. №11. С.1504-1512. РИНЦ
Даты:
Поступила в редакцию: | 31 окт. 2017 г. |
Опубликована в печати: | 1 нояб. 2017 г. |
Опубликована online: | 7 мар. 2018 г. |
Идентификаторы БД:
Web of science: | WOS:000426945200013 |
Scopus: | 2-s2.0-85043383571 |
РИНЦ: | 35544604 |
Chemical Abstracts: | 2018:416811 |
Chemical Abstracts (print): | 168:319443 |
OpenAlex: | W2790152565 |