Transport Properties of Ca-Doped Ln2NiO4 for Intermediate Temperature Solid Oxide Fuel Cells Cathodes and Catalytic Membranes for Hydrogen Production | Sciact - CRIS-system of Boreskov Institute of Catalysis

Transport Properties of Ca-Doped Ln2NiO4 for Intermediate Temperature Solid Oxide Fuel Cells Cathodes and Catalytic Membranes for Hydrogen Production Full article

Conference

10th International Conference on Sustainable Energy & Environmental Protection
27-30 Jun 2017 , Bled

Journal

International Journal of Hydrogen Energy
ISSN: 0360-3199 , E-ISSN: 1879-3487

Output data

Year: 2020, Volume: 45, Number: 25, Pages: 13625-13642 Pages count : 18 DOI: 10.1016/j.ijhydene.2018.03.039

Tags

Doped Ln2NiO4+δ, Electrochemical performance, Hydrogen production, Isotope exchange, MIEC membrane, SOFC cathode

Authors

Sadykov Vladislav A. ^1,2 , Pikalova Elena Yu. ^3,4 , Kolchugin Alexander A. ^3,4 , Fetisov Andrey V. ⁵ , Sadovskaya Ekaterina M. ^1,2 , Filonova Elena A. ⁴ , Eremeev Nikita F. ¹ , Goncharov Vladimir B. ¹ , Krasnov Alexey V. ¹ , Skriabin Pavel I. ¹ , Shmakov Alexander N. ^1,2,6 , Vinokurov Zakhar S. ¹ , Ishchenko Arcady V. ^1,2 , Pikalov Sergey M. ⁵

Affiliations

1	Boreskov Institute of Catalysis SB RAS, Pr. Akad. Lavrentieva 5, Novosibirsk, 630090, Russia
2	Novosibirsk State University, Pirogova Str. 2, Novosibirsk, 630090, Russia
3	Institute of High Temperature Electrochemistry, UB RAS, Akademicheskaya Str. 20, Yekaterinburg, 620137, Russia
4	Ural Federal University, Mira Str. 19, Yekaterinburg, 620002, Russia
5	Institute of Metallurgy, UB RAS, Amundsena Str. 101, Yekaterinburg, 620137, Russia
6	Budker Institute of Nuclear Physics SB RAS, Pr. Akad. Lavrentieva 11, Novosibirsk, 630090, Russia

Funding (4)

1	Federal Agency for Scientific Organizations	0303-2016-0013
2	Russian Science Foundation	16-13-00112
3	The Ministry of Education and Science of the Russian Federation	02.A03.21.0006
4	Federal Agency for Scientific Organizations	007-ГЗ/У4197/395

Novel methods were applied in this work to elucidate the structure evolution of Ln2-xCaxNiO4+δ oxides (Ln = La, Pr, Nd; x = 0, 0.3) and study their oxygen mobility. Relationship between cations state, structural, electrical, electrochemical and kinetic properties was revealed. In all doped materials the overall oxygen mobility characterized by Do declined by more than an order of magnitude due to decreasing the interstitial oxygen content and hampering cooperative mechanism of oxygen migration. For La nikelate additional slow diffusion channel appears with DO 5.4·10−14 cm2/s at 700 K. Correlation of electrochemical and oxygen transport properties was demonstrated. A high electrical conductivity (up to 120 S/cm at 700 K) in Ln1.7Ca0.3NiO4+δ (Ln = Pr, Nd) along with satisfactory oxygen mobility and electrochemical properties makes these materials promising for a wide row of electrochemical applications.

Sadykov V.A. , Pikalova E.Y. , Kolchugin A.A. , Fetisov A.V. , Sadovskaya E.M. , Filonova E.A. , Eremeev N.F. , Goncharov V.B. , Krasnov A.V. , Skriabin P.I. , Shmakov A.N. , Vinokurov Z.S. , Ishchenko A.V. , Pikalov S.M.
Transport Properties of Ca-Doped Ln2NiO4 for Intermediate Temperature Solid Oxide Fuel Cells Cathodes and Catalytic Membranes for Hydrogen Production
International Journal of Hydrogen Energy. 2020. V.45. N25. P.13625-13642. DOI: 10.1016/j.ijhydene.2018.03.039 WOS Scopus РИНЦ AN OpenAlex

Submitted:	Nov 30, 2017
Accepted:	Mar 6, 2018
Published online:	Mar 30, 2018
Published print:	May 7, 2020

Web of science:	WOS:000528272100008
Scopus:	2-s2.0-85044545897
Elibrary:	35501472
Chemical Abstracts:	2018:596556
OpenAlex:	W2794781189

DB	Citing
Scopus	31
Elibrary	2
Web of science	27
OpenAlex	29