Preparation of Zr(Mo,W)2O8 with a Larger Negative Thermal Expansion by Controlling the Thermal Decomposition of Zr(Mo,W)2(OH,Cl)2∙2H2O | Sciact - CRIS-system of Boreskov Institute of Catalysis

Preparation of Zr(Mo,W)2O8 with a Larger Negative Thermal Expansion by Controlling the Thermal Decomposition of Zr(Mo,W)2(OH,Cl)2∙2H2O Full article

Journal

Scientific Reports
, E-ISSN: 2045-2322

Output data

Year: 2018, Volume: 8, Number: 1, Article number : 5337, Pages count : 7 DOI: 10.1038/s41598-018-23529-6

Tags

MATERIAL CUBIC ZRMO2O8; ZRW2O8

Authors

Petrushina Mariya Yu. ^1,2 , Dedova Elena S. ^3,4 , Filatov Eugeny Yu. ^1,2 , Plyusnin Pavel E. ^1,2 , Korenev Sergei V. ^1,2 , Kulkov Sergei N. ^3,4 , Derevyannikova Elizaveta A. ^2,5 , Sharafutdinov Marat R. ^6,7 , Gubanov Alexander I. ^1,2

Affiliations

1	Nikolaev Institute of Inorganic Chemistry, Siberian Branch of the Russian Academy of Sciences, Academician Lavrentiev Prospekt 3, 630090, Novosibirsk, Russian Federation
2	Novosibirsk State University, Pirogova str. 2, 630090, Novosibirsk, Russian Federation
3	Institute of Strength Physics and Materials Science, Siberian Branch of the Russian Academy of Sciences, pr. Academicheskii 2/4, 634021, Tomsk, Russian Federation
4	Tomsk Polytechnic University, Lenin Avenue 30, 634050, Tomsk, Russian Federation
5	Boreskov Institute of Catalysis, Siberian Branch of the Russian Academy of Sciences, Acad. Lavrentiev Prospekt 5, 630090, Novosibirsk, Russian Federation
6	Institute of Solid State Chemistry and Mechanochemistry of the Siberian Branch of the Russian Academy of Sciences, Kutateladze 18, 630128, Novosibirsk, Russian Federation
7	Budker Institute of Nuclear Physics of the Siberian Branch of the Russian Academy of Sciences, Acad. Lavrentiev Prospekt 11, 630090, Novosibirsk, Russian Federation

Funding (4)

1	Russian Foundation for Basic Research	18-33-00493 (АААА-А18-118040590009-5)
2	The Ministry of Education and Science of the Russian Federation	73\2017
3	Federal Agency for Scientific Organizations
4	BP Chemicals Limited, Research Laboratory

Solid solutions of Zr(Mo,W)2O7(OH,Cl)2∙2H2O with a preset ratio of components were prepared by a hydrothermal method. The chemical composition of the solutions was determined by energy dispersive X-ray spectroscopy (EDX). For all the samples of ZrMoxW2−xO7(OH,Cl)2∙2H2O (x = 0.0, 0.2, 0.4, 0.6, 0.8, 1.0, 1.2, 1.4, 1.6, 1.8, and 2.0), TGA and in situ powder X-ray diffraction (PXRD) studies (300–1100 K) were conducted. For each case, the boundaries of the transformations were determined: Zr(Mo,W)2O7(OH,Cl)2∙2H2O → orthorhombic-ZrMoxW2−xO8 (425–525 K), orthorhombic-ZrMoxW2−xO8 → cubic-ZrMoxW2−xO8 (700–850 K), cubic-ZrMoxW2−xO8 → trigonal-ZrMoxW2−xO8 (800–1050 K for x > 1) and cubic-ZrMoxW2−xO8 → oxides (1000–1075 K for x ≤ 1). The cell parameters of the disordered cubic-ZrMoxW2−xO8 (space group Pa-3) were measured within 300–900 K, and the thermal expansion coefficients were calculated: −3.5∙10−6 – −4.5∙10−6 K−1. For the ordered ZrMo1.8W0.2O8 (space group P213), a negative thermal expansion (NTE) coefficient −9.6∙10−6 K−1 (300-400 K) was calculated. Orthorhombic-ZrW2O8 is formed upon the decomposition of ZrW2O7(OH,Cl)2∙2H2O within 500–800 K.

Petrushina M.Y. , Dedova E.S. , Filatov E.Y. , Plyusnin P.E. , Korenev S.V. , Kulkov S.N. , Derevyannikova E.A. , Sharafutdinov M.R. , Gubanov A.I.
Preparation of Zr(Mo,W)2O8 with a Larger Negative Thermal Expansion by Controlling the Thermal Decomposition of Zr(Mo,W)2(OH,Cl)2∙2H2O

Scientific Reports. 2018. V.8. N1. 5337 :1-7. DOI: 10.1038/s41598-018-23529-6 WOS Scopus РИНЦ AN PMID OpenAlex

Full text from publisher

Submitted:	Nov 23, 2017
Accepted:	Mar 14, 2018
Published online:	Mar 28, 2018
Published print:	Dec 1, 2018

Web of science:	WOS:000428518900034
Scopus:	2-s2.0-85044542955
Elibrary:	35503013
Chemical Abstracts:	2018:1695186
PMID:	29593240
OpenAlex:	W2795071977

DB	Citing
Web of science	7
Scopus	10
Elibrary	9
OpenAlex	9