Formation of Chiral Structures in Photoinitiated Formose Reaction | Sciact - CRIS-system of Boreskov Institute of Catalysis

Formation of Chiral Structures in Photoinitiated Formose Reaction Full article

Journal

High Energy Chemistry
ISSN: 0018-1439

Output data

Year: 2018, Volume: 52, Number: 2, Pages: 108-116 Pages count : 9 DOI: 10.1134/S0018143918020145

Tags

biopoiesis, chirality, formaldehyde, formose reaction, photoionization

Authors

Stovbun S.V. ¹ , Skoblin A.A. ¹ , Zanin A.M. ¹ , Tverdislov V.A. ² , Taran O.P. ^3,4 , Parmon V.N. ^3,5,6

Affiliations

1	Semenov Institute of Chemical Physics, Russian Academy of Sciences, Moscow, Russia
2	Faculty of Physics, Moscow State University, Moscow, Russia
3	Boreskov Institute of Catalysis, Siberian Branch, Russian Academy of Sciences, Novosibirsk, Russia
4	Novosibirsk State Technical University, Novosibirsk, Russia
5	Novosibirsk State University, Novosibirsk, Russia
6	Tomsk State University, Tomsk, Russia

The possibility to synthesize biologically important sugars and other chiral compounds without any initiators in the UV-initiated reaction of formaldehyde in aqueous solution has been shown for the first time. An optically active condensed phase due to an sp3-hybridized carbon atom has been detected. It has been shown that this phase is formed due to the spatial cleavage of antipodes in the racemate, similar to the cleavage of enantiomers following the sign of chirality in the known experiments of Pasteur. The results have been obtained under the conditions that correspond to modern ideas about the form and vector of prebiological evolution and, therefore, can be of fundamental importance for understanding the processes of biopoiesis.

Stovbun S.V. , Skoblin A.A. , Zanin A.M. , Tverdislov V.A. , Taran O.P. , Parmon V.N.
Formation of Chiral Structures in Photoinitiated Formose Reaction
High Energy Chemistry. 2018. V.52. N2. P.108-116. DOI: 10.1134/S0018143918020145 WOS Scopus РИНЦ AN OpenAlex

Стовбун С.В. , Скоблин А.А. , Занин А.М. , Твердислов В.А. , Таран О.П. , Пармон В.Н.
Образование хиральных структур в фотоинициированной формозной реакции
Химия высоких энергий. 2018. Т.52. №2. С.94-102. DOI: 10.7868/s0023119718020023 РИНЦ OpenAlex

Submitted:	Sep 7, 2017
Published print:	Mar 1, 2018
Published online:	Mar 28, 2018

Web of science:	WOS:000428559400002
Scopus:	2-s2.0-85044787503
Elibrary:	35488950
Chemical Abstracts:	2018:665008
OpenAlex:	W2803632771

DB	Citing
Web of science	5
Scopus	4
Elibrary	4
OpenAlex	4