Changing the Characteristics and Properties of Zeolite Y and Nano-Anatase in the Formation of a Nano-Anatase/Y Composite with Improved Photocatalytic and Adsorption Properties | Sciact - CRIS-system of Boreskov Institute of Catalysis

Changing the Characteristics and Properties of Zeolite Y and Nano-Anatase in the Formation of a Nano-Anatase/Y Composite with Improved Photocatalytic and Adsorption Properties Full article

Journal

Applied Nanoscience
ISSN: 2190-5509 , E-ISSN: 2190-5517

Output data

Year: 2018, Volume: 8, Number: 1-2, Pages: 19-31 Pages count : 13 DOI: 10.1007/s13204-018-0648-5

Tags

Zeolite Y; Nanosized titanium dioxide; Nanocomposite; Crystalline structure and microstructure; Adsorption and photocatalytic properties

Authors

Domoroshchina E.N. ¹ , Chernyshev V.V. ² , Kuz’micheva G.M. ¹ , Dorokhov A.V. ¹ , Pirutko L.V. ³ , Kravchenko G.V. ¹ , Chumakov R.B. ⁴

Affiliations

1	Department of Materials Science and Technology of Functional Materials and Structures, Moscow Technological University, MITHT, 86 Vernadsky Avenue, Moscow, Russia 119571
2	Lomonosov Moscow State University, GSP-1, 1-3 Leninskiye Gory, Moscow, Russia 119991
3	Boreskov Institute of Catalysis, Siberian Branch of the Russian Academy of Sciences, pr. Lavrentieva 5, Novosibirsk, Russia 630090
4	National Research Center ‘Kurchatov Institute’, 1, Akademika Kurchatova pl, Moscow, Russia 123182

Funding (2)

1	Russian Foundation for Basic Research	15-03-01289
2	The Ministry of Education and Science of the Russian Federation	14.616.21.0069 (RFMEFI61616X0069)

Zeolite Y and the NTD/Y nanocomposite, which were synthesized in situ (the addition of zeolite Y to the reaction mixture in the course of the synthesis of NTD by the sulfate method), were studied by a variety of methods. The decrease in the particle size (scanning electron microscopy) and the water content in pores (X-ray powder diffraction study, the full-profile Rietveld method, IR spectroscopy, differential scanning calorimetry), the increase in OH groups content and the decrease in the water content on the surface of zeolite (X-ray photoelectron spectroscopy) in the composition of NTD/Y compared to the initial zeolite Y were all established. A larger specific surface area of NTD/Y (Brunauer-Emmet-Teller method) compared to the initial zeolite Y is due to the fact that zeolite Y in the nanocomposite contains a smaller amount of water because of the synthesis conditions and the presence of nanocrystalline NTD on the surface of zeolite particles. It was found that NTD/Y nanocomposite exhibits a higher photocatalytic activity in the model decomposition reaction of methyl orange under UV and adsorption capacity for the extraction of P(V) and As(V) ions from aqueous media compared to the initial zeolite and pure NTD obtained under the same conditions, which differs from NTD/Y by the larger particle size, the smaller specific surface and the smaller content of OH groups and water on the surface. The role of Bronsted and Lewis centers in the realization of properties is discussed.

Domoroshchina E.N. , Chernyshev V.V. , Kuz’micheva G.M. , Dorokhov A.V. , Pirutko L.V. , Kravchenko G.V. , Chumakov R.B.
Changing the Characteristics and Properties of Zeolite Y and Nano-Anatase in the Formation of a Nano-Anatase/Y Composite with Improved Photocatalytic and Adsorption Properties

Applied Nanoscience. 2018. V.8. N1-2. P.19-31. DOI: 10.1007/s13204-018-0648-5 WOS Scopus РИНЦ РИНЦ ANCAN OpenAlex

Full text from publisher

Submitted:	Jul 21, 2017
Accepted:	Dec 4, 2017
Published print:	Feb 1, 2018
Published online:	Feb 3, 2018

Web of science:	WOS:000429242500003
Scopus:	2-s2.0-85061713491
Elibrary:	36785430 \| 38670208
Chemical Abstracts:	2018:218700
Chemical Abstracts (print):	168:287909
OpenAlex:	W2792830039

DB	Citing
Web of science	14
Scopus	16
Elibrary	16
OpenAlex	16