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L-Methioninium Picrate Full article

Journal Spectrochimica Acta Part A: Molecular and Biomolecular Spectroscopy
ISSN: 1386-1425 , E-ISSN: 1873-3557
Output data Year: 2015, Volume: 142, Pages: 344-349 Pages count : 6 DOI: 10.1016/j.saa.2015.02.036
Tags Crystal structurel, -Methioninium picrate, NLO crystals, Vibrational spectra
Authors Ghazaryan V.V. 1 , Zakharov B.A. 2,3 , Boldyreva E.V. 2,3 , Petrosyan A.M. 1
Affiliations
1 Institute of Applied Problems of Physics, NAS of Armenia, 25 Nersessyan Str., Yerevan, Armenia
2 Institute of Solid State Chemistry, Siberian Branch of the Russian Academy of Sciences, Kutateladze 18, Novosibirsk, Russian Federation
3 REC-008, Novosibirsk State University, Pirogova 2, Novosibirsk, Russian Federation

Abstract: Single crystals of l-methioninium picrate were obtained by evaporation of aqueous solution containing equimolar quantities of each component. l-Methioninium picrate crystallizes in the monoclinic system (space group P21, Z = 2). The asymmetric unit contains one l-methioninium cation and one picrate anion. The carboxyl group of the cation forms an O-H⋯O hydrogen bond with the phenoxy oxygen atom and has an O⋯O distance of 2.669(3) Å. The protonated amino group of the l-methioninium cation forms N-H⋯O hydrogen bonds with the phenoxy oxygen atom of the picrate anion and the carbonyl oxygen atom of the symmetry related cation. The infrared and Raman spectra are recorded and discussed.
Cite: Ghazaryan V.V. , Zakharov B.A. , Boldyreva E.V. , Petrosyan A.M.
L-Methioninium Picrate
Spectrochimica Acta Part A: Molecular and Biomolecular Spectroscopy. 2015. V.142. P.344-349. DOI: 10.1016/j.saa.2015.02.036 WOS Scopus РИНЦ ANCAN OpenAlex
Dates:
Submitted: Oct 17, 2014
Accepted: Feb 6, 2015
Published online: Feb 14, 2015
Published print: May 1, 2015
Identifiers:
Web of science: WOS:000351980400044
Scopus: 2-s2.0-84923371393
Elibrary: 24010318
Chemical Abstracts: 2015:284007
Chemical Abstracts (print): 162:340763
OpenAlex: W2053405851
Citing:
DB Citing
Web of science 19
Scopus 19
OpenAlex 21
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