[6]-[9]Metacyclophanes: Synthesis, Crystal Structures, and NMR and UV Spectroscopy | Sciact - CRIS-system of Boreskov Institute of Catalysis

[6]-[9]Metacyclophanes: Synthesis, Crystal Structures, and NMR and UV Spectroscopy Full article

Journal

European Journal of Organic Chemistry
ISSN: 1434-193X , E-ISSN: 1099-0690

Output data

Year: 2017, Volume: 2017, Number: 36, Pages: 5410-5416 Pages count : 7 DOI: 10.1002/ejoc.201700946

Tags

Aromaticity, Cyclophanes, N-Methylpyridinium salts, Nitropyridines, Rearrangement

Authors

Shuvalov Vladislav Yu. ¹ , Eltsov Ilia V. ² , Tumanov Nikolay A. ^2,4 , Boldyreva Elena V. ² , Nefedov Andrey A. ³ , Sagitullina Galina P. ¹

Affiliations

1	Department of Organic Chemistry, F. M. Dostoevsky Omsk State University, 644077 Omsk, Russian Federation
2	Novosibirsk State University, 630090 Novosibirsk, Russian Federation
3	N. N. Vorozhtsov Institute of Organic Chemistry, Siberian Branch of the Russian Academy of Sciences
4	Department of Chemistry, University of Namur, rue de Bruxelles 61, 5000 Namur, Belgium

Funding (1)

Russian Foundation for Basic Research

16-43-550144 (АААА-А16-116040810158-3)

Metacyclophanes have been developed as non-planar aromatic compounds with unusual physical properties. [6]–[9]Metacyclophanes were synthesized by rearrangement of 3-nitro(perhydrocycloalka)[b]pyridinium salts, and analysis of their spectroscopic data and X-ray diffraction patterns indicates the aromaticity and flexibility of their benzene rings. The effectiveness and simplicity of the synthesis makes it possible to use them as available precursors in the synthesis of retinoids, indolophanes, and carbazolophanes. © 2017 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim

Shuvalov V.Y. , Eltsov I.V. , Tumanov N.A. , Boldyreva E.V. , Nefedov A.A. , Sagitullina G.P.
[6]-[9]Metacyclophanes: Synthesis, Crystal Structures, and NMR and UV Spectroscopy
European Journal of Organic Chemistry. 2017. V.2017. N36. P.5410-5416. DOI: 10.1002/ejoc.201700946 WOS Scopus РИНЦ ANCAN OpenAlex

Submitted:	Jul 7, 2017
Published online:	Aug 11, 2017
Published print:	Oct 2, 2017

Web of science:	WOS:000412127100006
Scopus:	2-s2.0-85030169118
Elibrary:	31051478
Chemical Abstracts:	2017:1577113
Chemical Abstracts (print):	167:495881
OpenAlex:	W2742255552

DB	Citing
Web of science	3
Scopus	3
OpenAlex	3