Effect of the Acid–Base Properties of Zr,Al-Pillared Clays on the Catalytic Performances in the Reaction of Propylene Oxide with Methanol | Sciact - CRIS-system of Boreskov Institute of Catalysis

Effect of the Acid–Base Properties of Zr,Al-Pillared Clays on the Catalytic Performances in the Reaction of Propylene Oxide with Methanol Full article

Journal

Applied Catalysis B: Environmental
ISSN: 0926-3373 , E-ISSN: 1873-3883

Output data

Year: 2011, Volume: 104, Number: 1-2, Pages: 54-63 Pages count : 10 DOI: 10.1016/j.apcatb.2011.02.028

Tags

Methanol, Propylene glycol methyl ether, Propylene oxide, Zr,Al-pillared clays

Authors

Timofeeva M.N. ¹ , Panchenko V.N. ¹ , Gil A. ² , Doronin V.P. ³ , Golovin A.V. ⁴ , Andreev A.S. ⁴ , Likholobov V.A. ^3,5

Affiliations

1	Boreskov Institute of Catalysis SB RAS, Prospekt Akad. Lavrentieva 5, 630090, Novosibirsk, Russian Federation
2	Department of Applied Chemistry, Public University of Navarra, Campus of Arrosadıa s/n, 31006 Pamplona, Spain
3	Institute of Hydrocarbons Processing SB RAS, Neftezavodskaya ul. 54, 644040, Omsk, Russian Federation
4	Novosibirsk State University, Prospekt Akad. Koptyuga 2, Novosibirsk 630090, Russian Federation
5	Omsk Scientific Centre SB RAS, Neftezavodskaya ul. 54, 644040, Omsk, Russian Federation

Funding (1)

Russian Foundation for Basic Research

08-08-00729

A series of Zr,Al-pillared interlayered clays (Zr,Al-PILCs) have been prepared and characterized by X-ray diffraction, elemental analysis, FT-IR and N2-adsorption/desorption analyses, 27Al NMR(MAS), FT-IR spectroscopy using pyridine, PhCN and CDCl3 as probe molecules. It was found that textural and physicochemical properties of Zr,Al-PILCs depend on Zr content in clay. The relationship between the acid–base properties and catalytic performances of Zr,Al-PILCs was revealed in the synthesis of propylene glycol methyl ether from methanol and propylene oxide. The results show that the conversion of propylene oxide and the selectivity to 1-methoxy-2-propanol decrease with increasing the amount of zirconium in Zr,Al-PILCs due to the change in acid–base properties.

Timofeeva M.N. , Panchenko V.N. , Gil A. , Doronin V.P. , Golovin A.V. , Andreev A.S. , Likholobov V.A.
Effect of the Acid–Base Properties of Zr,Al-Pillared Clays on the Catalytic Performances in the Reaction of Propylene Oxide with Methanol
Applied Catalysis B: Environmental. 2011. V.104. N1-2. P.54-63. DOI: 10.1016/j.apcatb.2011.02.028 WOS Scopus РИНЦ ANCAN OpenAlex

Submitted:	Nov 29, 2010
Published online:	Mar 1, 2011
Published print:	Apr 1, 2011
Accepted:	Nov 22, 2011

Web of science:	WOS:000290704500008
Scopus:	2-s2.0-79954418310
Elibrary:	16999186
Chemical Abstracts:	2011:480949
Chemical Abstracts (print):	154:543043
OpenAlex:	W1967860492

DB	Citing
Web of science	18
Scopus	19
Elibrary	18
OpenAlex	20