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The Oxidative Dehydrogenation of Ethane: Convectional vs Microwave Heating of Ba - Containing Catalysts Научная публикация

Журнал Chemical Engineering and Processing: Process Intensification
ISSN: 0255-2701
Вых. Данные Год: 2018, Том: 129, Страницы: 103-108 Страниц : 6 DOI: 10.1016/j.cep.2018.05.006
Ключевые слова Oxidative dehydrogenation Ethane Microwave heating Catalyst
Авторы Bolotov Vasiliy A. 1 , Chesnokov Vladimir V. 1 , Tanashev Yuriy Y. 1 , Parmon Valentin N. 1,2
Организации
1 Boreskov Institute of Catalysis, Siberian Branch, Russian Academy of Sciences, pr. Lavrentieva 5, 630090, Novosibirsk, Russia
2 Novosibirsk National Research State University, Novosibirsk-90, 2 Pirogova Str., 630090, Novosibirsk, Russia

Информация о финансировании (1)

1 Российский научный фонд 17-73-30032

Реферат: The influence of heating method on oxidative dehydrogenation of ethane (ODE) over BaO–CeO2–ZrO2 and BaCl2–TiO2–SnO2 catalysts was studied. Noticeable differences were observed at the ODE under conventional heating and microwave (MW) heating when only the granules of catalyst but not the surrounding gas mixture are heated. The MW heating of the BaO–CeO2–ZrO2 catalyst resulted in a decrease in selectivity to carbon dioxide and in an increase in selectivity to carbon monoxide. Supposedly, the conventional heating led to gas-phase complete oxidation of carbon monoxide to carbon dioxide. The MW heating of the BaCl2–TiO2–SnO2 catalyst suppressed almost completely parallel and consecutive deep oxidation of ethylene but selectivity to ethylene increased remarkably. The study demonstrates potentialities of the MW heating in enhancing the efficiency of ODE. The observed phenomena can be accounted for the effective “quenching” of the target ODE product via inhibiting undesirable homogeneous reactions in the gas phase.
Библиографическая ссылка: Bolotov V.A. , Chesnokov V.V. , Tanashev Y.Y. , Parmon V.N.
The Oxidative Dehydrogenation of Ethane: Convectional vs Microwave Heating of Ba - Containing Catalysts
Chemical Engineering and Processing: Process Intensification. 2018. V.129. P.103-108. DOI: 10.1016/j.cep.2018.05.006 WOS Scopus РИНЦ CAPlusCA OpenAlex
Даты:
Поступила в редакцию: 30 дек. 2017 г.
Принята к публикации: 11 мая 2018 г.
Опубликована online: 21 мая 2018 г.
Опубликована в печати: 1 июл. 2018 г.
Идентификаторы БД:
Web of science: WOS:000435059000013
Scopus: 2-s2.0-85047152308
РИНЦ: 35482820
Chemical Abstracts: 2018:995735
Chemical Abstracts (print): 172:150253
OpenAlex: W2803867183
Цитирование в БД:
БД Цитирований
Web of science 13
Scopus 14
РИНЦ 13
OpenAlex 13
Альметрики: