Design of Ag-CeO2/SiO2 Catalyst for Oxidative Dehydrogenation of Ethanol: Control of Ag–CeO2 Interfacial Interaction | Sciact - CRIS-system of Boreskov Institute of Catalysis

Design of Ag-CeO2/SiO2 Catalyst for Oxidative Dehydrogenation of Ethanol: Control of Ag–CeO2 Interfacial Interaction Full article

Journal

Catalysis Today
ISSN: 0920-5861 , E-ISSN: 1873-4308

Output data

Year: 2019, Volume: 333, Pages: 2-9 Pages count : 8 DOI: 10.1016/j.cattod.2018.05.014

Tags

silver, ceria, oxidative dehydrogenation of ethanol, Ag–CeO2 interaction

Authors

Grabchenko M.V. ¹ , Mamontov G.V. ¹ , Zaikovskii V.I. ^2,3 , La Parola V. ⁴ , Liotta L.F. ⁴ , Vodyankina O.V. ¹

Affiliations

1	Tomsk State University, 36 Lenin ave., 634050, Tomsk, Russia
2	Boreskov Institute of Catalysis, 5 pr. Lavrentiev, 630090, Novosibirsk, Russia
3	Novosibirsk State University, Pirogova Str. 2, 630090, Novosibirsk, Russia
4	Istituto per lo Studio dei Materiali Nanostrutturati (ISMN)-CNR, via Ugo La Malfa, 153, 90146, Palermo, Italy

Funding (1)

The Ministry of Education and Science of the Russian Federation

МК-2015.2017.3

Three Ag-CeO2/SiO2 catalysts were prepared by different methods, namely, sequential impregnation, co-impregnation and impregnation of pre-reduced CeO2/SiO2 and are tested in the oxidative dehydrogenation of ethanol. The order of introduction of silver and ceria precursors is found to influence the catalytic activity that increases in the order of preparation method: sequential impregnation < co-impregnation < impregnation of pre-reduced CeO2/SiO2. Results of TPR-H2, TEM HR, XPS and Raman characterizations show the best interfacial Ag–CeO2 interaction and highest defectiveness of CeO2 nanoparticles in the catalyst prepared by impregnation of pre-reduced CeO2/SiO2. A correlation between Ag–CeO2 interaction and catalytic activity is found in the series of Ag-CeO2/SiO2 catalysts depending on the preparation method. Enhanced Ag–CeO2 interfacial interaction leads to increased activity in oxidative dehydrogenation of ethanol.

Grabchenko M.V. , Mamontov G.V. , Zaikovskii V.I. , La Parola V. , Liotta L.F. , Vodyankina O.V.
Design of Ag-CeO2/SiO2 Catalyst for Oxidative Dehydrogenation of Ethanol: Control of Ag–CeO2 Interfacial Interaction
Catalysis Today. 2019. V.333. P.2-9. DOI: 10.1016/j.cattod.2018.05.014 WOS Scopus РИНЦ ANCAN OpenAlex

Submitted:	Dec 13, 2017
Accepted:	May 6, 2018
Published online:	May 7, 2018
Published print:	Aug 1, 2019

Web of science:	WOS:000470828100002
Scopus:	2-s2.0-85046752349
Elibrary:	41608832
Chemical Abstracts:	2018:964860
Chemical Abstracts (print):	171:28486
OpenAlex:	W2801452384

DB	Citing
Scopus	41
Elibrary	47
Web of science	47
OpenAlex	46