Formation of Chiral Structures in UV-Initiated Formose Reaction | Sciact - CRIS-system of Boreskov Institute of Catalysis

Formation of Chiral Structures in UV-Initiated Formose Reaction Full article

Journal

Doklady Physical Chemistry
ISSN: 0012-5016 , E-ISSN: 1608-3121

Output data

Year: 2018, Volume: 479, Number: 1-2, Pages: 57-60 Pages count : 4 DOI: 10.1134/S001250161803003X

Tags

FORMALDEHYDE

Authors

Stovbun S. V. ¹ , Skoblin A. A. ¹ , Zanin A. M. ¹ , Tverdislov V. A. ² , Taran O. P. ^3,4 , Parmon V. N. ^3,5,6

Affiliations

1	Semenov Institute of Chemical Physics, Russian Academy of Sciences, Moscow, 119991 Russia
2	Faculty of Physics, Moscow State University, Moscow, 119991 Russia
3	Boreskov Institute of Catalysis, Siberian Branch, Russian Academy of Sciences, Novosibirsk, 630090 Russia
4	Novosibirsk State Technical University, Novosibirsk, 630073 Russia
5	Novosibirsk State University, Novosibirsk, 630090 Russia
6	Tomsk State University, Tomsk, 634050 Russia

Funding (1)

Federal Agency for Scientific Organizations

V.47.1.3.

It has been found that the UV-initiated formose reaction in an extremely concentrated aqueous solution of formaldehyde gives sugars and other biologically significant chiral compounds with sp3-hybridized carbon atom. The reaction leads to an optically active condensed phase, which is a result of the spontaneous spatial separation of enantiomers in the racemate into the antipodes, similarly to the separation of enantiomers of different chirality sign in the famous Pasteur experiments. In our opinion, such a scenario is as close as possible to the actually realized de novo scenario of synthesis of chiral prebiotic molecules and matrices.

Stovbun S.V. , Skoblin A.A. , Zanin A.M. , Tverdislov V.A. , Taran O.P. , Parmon V.N.
Formation of Chiral Structures in UV-Initiated Formose Reaction
Doklady Physical Chemistry. 2018. V.479. N1-2. P.57-60. DOI: 10.1134/S001250161803003X WOS Scopus РИНЦ AN OpenAlex

Стовбун С.В. , Скоблин А.А. , Занин А.М. , Твердислов В.А. , Таран О.П. , Пармон В.Н.
Формирование хиральных структур в УФ-инициированной формозной реакции
Доклады Академии наук. 2018. Т.479. №3. С.288-292. DOI: 10.7868/s0869565218090116 РИНЦ OpenAlex

Submitted:	Nov 2, 2017
Published print:	Mar 1, 2018
Published online:	May 18, 2018

Web of science:	WOS:000432619100003
Scopus:	2-s2.0-85047245494
Elibrary:	35521904
Chemical Abstracts:	2018:972588
OpenAlex:	W2943401189

DB	Citing
Web of science	3
Scopus	4
Elibrary	3
OpenAlex	4