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Heterogeneous Catalysts for Hydrogenation of CO2 and Bicarbonates to Formic acid and Formates Обзор

Журнал Catalysis Reviews: Science and Engineering
ISSN: 0161-4940 , E-ISSN: 1520-5703
Вых. Данные Год: 2018, Том: 60, Номер: 4, Страницы: 566-593 Страниц : 28 DOI: 10.1080/01614940.2018.1476806
Ключевые слова CO2 hydrogenation, formic acid, heterogeneous catalysts, production
Авторы Bulushev Dmitri A. 1,2 , Ross Julian R.H. 3
Организации
1 Laboratory of Catalytic Methods of Transformation of Solar Energy, Boreskov Institute of Catalysis, Novosibirsk, Russia
2 Laboratory of Carbon Nanomaterials, Novosibirsk State University, Novosibirsk, Russia
3 Chemical & Environmental Sciences Department, University of Limerick, Limerick, Ireland

Информация о финансировании (1)

1 Российский научный фонд 17-73-30032

Реферат: Formic acid and formates are often produced by hydrogenation of CO2 with hydrogen over homogeneous catalysts. The present review reports recent achievements in utilization of heterogeneous catalysts. It shows that highly dispersed supported metal catalysts are able to carry out this reaction by providing activation of hydrogen on the metal sites and activation of CO2 or bicarbonate on the support sites. Important advances have recently been achieved through utilization of catalysts using CxNy materials as supports. The high activity of these catalysts could be assigned to their ability to stabilize the active metal in a state of single-metal atoms or heterogenized metal complexes, which may demonstrate a higher activity than metal atoms on the surface of metal nanoparticles.
Библиографическая ссылка: Bulushev D.A. , Ross J.R.H.
Heterogeneous Catalysts for Hydrogenation of CO2 and Bicarbonates to Formic acid and Formates
Catalysis Reviews: Science and Engineering. 2018. V.60. N4. P.566-593. DOI: 10.1080/01614940.2018.1476806 WOS Scopus РИНЦ CAPlus OpenAlex
Даты:
Поступила в редакцию: 27 февр. 2018 г.
Принята к публикации: 10 мая 2018 г.
Опубликована online: 1 июн. 2018 г.
Опубликована в печати: 2 окт. 2018 г.
Идентификаторы БД:
Web of science: WOS:000443846400002
Scopus: 2-s2.0-85047914440
РИНЦ: 35745647
Chemical Abstracts: 2018:1064638
OpenAlex: W2806106678
Цитирование в БД:
БД Цитирований
Web of science 121
Scopus 128
OpenAlex 126
Альметрики: