Mechanism of Heterogeneous Catalytic Oxidation of Organic Compounds to Carboxylic Acids Review
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Russian Chemical Reviews
ISSN: 0036-021X , E-ISSN: 1468-4837 |
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| Output data | Year: 2018, Volume: 87, Number: 6, Pages: 586-603 Pages count : 18 DOI: 10.1070/RCR4779 | ||
| Tags | SUPPORTED VANADIUM-OXIDE; TI-O CATALYST; VAPOR-PHASE OXIDATION; IN-SITU FTIR; CRYSTALLINE CRV0.95P0.05O4 CATALYST; BETA-PICOLINE OXIDATION; MIXED-METAL OXIDES; SELECTIVE OXIDATION; ACRYLIC-ACID; V2O5/TIO2 CATALYSTS | ||
| Authors |
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| Affiliations |
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Funding (1)
| 1 | Federal Agency for Scientific Organizations | 0303-2016-0006 (V.44.1.6) |
Abstract:
The results of studies on the mechanism of heterogeneous catalytic oxidation of organic compounds of different chemical structure to carboxylic acids are analyzed and generalized. The concept developed by Academician G.K.Boreskov, according to which the direction of the reaction is governed by the structure and bond energy of surface intermediates, was confirmed taking the title processes as examples. Quantitative criteria of the bond energies of surface compounds of oxidizable reactants, reaction products and oxygen that determine the selective course of the reaction are presented.
The bibliography includes 195 references.
Cite:
Andrushkevich T.V.
, Chesalov Y.A.
Mechanism of Heterogeneous Catalytic Oxidation of Organic Compounds to Carboxylic Acids
Russian Chemical Reviews. 2018. V.87. N6. P.586-603. DOI: 10.1070/RCR4779 WOS Scopus РИНЦ OpenAlex AN
Mechanism of Heterogeneous Catalytic Oxidation of Organic Compounds to Carboxylic Acids
Russian Chemical Reviews. 2018. V.87. N6. P.586-603. DOI: 10.1070/RCR4779 WOS Scopus РИНЦ OpenAlex AN
Original:
Андрушкевич Т.В.
, Чесалов Ю.А.
Механизм гетерогенно-каталитического окисления органических соединений в карбоновые кислоты
Успехи химии. 2018. Т.87. №6. С.586-603. РИНЦ
Механизм гетерогенно-каталитического окисления органических соединений в карбоновые кислоты
Успехи химии. 2018. Т.87. №6. С.586-603. РИНЦ
Dates:
| Submitted: | Aug 22, 2017 |
| Published online: | May 31, 2018 |
| Published print: | Jun 30, 2018 |
Identifiers:
| ≡ Web of science: | WOS:000437806900003 |
| ≡ Scopus: | 2-s2.0-85048052327 |
| ≡ Elibrary: | 39130174 |
| ≡ OpenAlex: | W2791146391 |
| ≡ Chemical Abstracts: | 2018:1986100 |