A Study on Structural Features of Bimetallic Pd-M/C (M: Zn, Ga, Ag) Catalysts for Liquid-Phase Selective Hydrogenation of Acetylene Full article
Journal |
Applied Catalysis A: General
ISSN: 0926-860X , E-ISSN: 1873-3875 |
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Output data | Year: 2018, Volume: 563, Pages: 18-27 Pages count : 10 DOI: 10.1016/j.apcata.2018.06.029 | ||||||||||
Tags | Liquid-phase hydrogenation of acetylene; palladium catalyst; bimetallic catalysts; metal-metal interaction; carbonaceous support | ||||||||||
Authors |
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Affiliations |
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Funding (1)
1 | Russian Foundation for Basic Research | 17-33-50019 |
Abstract:
The present work is devoted to the study of doping effects of zinc, gallium and silver on the structure of active sites and catalytic properties of carbon-supported 0.5 wt% Pd catalysts in the liquid-phase selective hydrogenation of acetylene to ethylene. Carbonaceous graphite-like material Sibunit was used as a support. The reaction was performed in a medium of N-methyl-2-pyrrolidone at 55 °C. It was shown that the bimetallic Pd-Zn/C, Pd-Ga/C and Pd-Ag/C catalysts exhibit better activity and selectivity towards target product if compare with the monometallic Pd/C catalyst. The ethylene yield increases in a row as follows: Pd/C (19%) < Pd-Ag/C (34%) < Pd-Ga/C (42%) < Pd-Zn/C (53%). Using X-ray absorption spectroscopy and transmission electron microscopy it was found that an improvement of the selectivity is stipulated by the formation of bimetallic PdZn, PdxGay and PdAg nanophases. In the case of Pd-Zn/C and Pd-Ag/C systems, an increased distance between neighboring Pd atoms (2.82 – 2.89 Å) in relation with monometallic Pd/C, where this distance is 2.72 Å, was observed. The higher activity of modified bimetallic systems is connected with increased number of active sites due to enhanced dispersity of supported palladium doped with second metal.
Cite:
Glyzdova D.V.
, Vedyagin A.A.
, Tsapina A.M.
, Kaichev V.V.
, Trigub A.L.
, Trenikhin M.V.
, Shlyapin D.A.
, Tsyrulnikov P.G.
, Lavrenov A.V.
A Study on Structural Features of Bimetallic Pd-M/C (M: Zn, Ga, Ag) Catalysts for Liquid-Phase Selective Hydrogenation of Acetylene
Applied Catalysis A: General. 2018. V.563. P.18-27. DOI: 10.1016/j.apcata.2018.06.029 WOS Scopus РИНЦ AN OpenAlex
A Study on Structural Features of Bimetallic Pd-M/C (M: Zn, Ga, Ag) Catalysts for Liquid-Phase Selective Hydrogenation of Acetylene
Applied Catalysis A: General. 2018. V.563. P.18-27. DOI: 10.1016/j.apcata.2018.06.029 WOS Scopus РИНЦ AN OpenAlex
Dates:
Submitted: | Apr 21, 2018 |
Accepted: | Jun 23, 2018 |
Published online: | Jun 27, 2018 |
Published print: | Aug 1, 2018 |
Identifiers:
Web of science: | WOS:000441856100003 |
Scopus: | 2-s2.0-85049077516 |
Elibrary: | 35752044 |
Chemical Abstracts: | 2018:1255020 |
OpenAlex: | W2810403817 |