Autoamplification-Enhanced Oxidative Kinetic Resolution of sec-Alcohols and Alkyl Mandelates, and Its Kinetic Model Научная публикация
| Журнал |
ChemCatChem
ISSN: 1867-3880 , E-ISSN: 1867-3899 |
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| Вых. Данные | Год: 2018, Том: 10, Номер: 12, Страницы: 2693-2699 Страниц : 7 DOI: 10.1002/cctc.201800180 | ||||
| Ключевые слова | asymmetric autoamplification, chirality, hydrogen peroxide, kinetic resolution, manganese | ||||
| Авторы |
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| Организации |
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Информация о финансировании (2)
| 1 | Российский фонд фундаментальных исследований | 16-29-10666 |
| 2 | Министерство науки и высшего образования Российской Федерации (с 15 мая 2018) | ГЗ-2017-2020 |
Реферат:
In this contribution, the new dynamic nonlinear effect in asymmetric catalysis is discussed, manifesting itself in the oxidative kinetic resolution (OKR) of racemic secondary benzylic alcohols and alkyl mandelates with H2O2 in the presence of chiral Mn-based catalyst, with the apparent selectivity factor (k(rel)) of the resolution being nonconstant over the reaction course. Typically, the initial growth of k(rel) is changed into decay at high conversions. In this contribution, we demonstrate the oxidative kinetic resolution of various substrates bearing sec-alcoholic moieties, with the k(rel) varying in different manners with increasing substrate conversion. We also present the predictive kinetic model of OKR with participation of asymmetric autoamplification. The influence of substrate and catalyst structure, as well as solvents and additives, on the behavior of k(rel) variation, is discussed.
Библиографическая ссылка:
Talsi E.P.
, Bryliakov K.P.
Autoamplification-Enhanced Oxidative Kinetic Resolution of sec-Alcohols and Alkyl Mandelates, and Its Kinetic Model
ChemCatChem. 2018. V.10. N12. P.2693-2699. DOI: 10.1002/cctc.201800180 WOS Scopus РИНЦ CAPlusCA OpenAlex
Autoamplification-Enhanced Oxidative Kinetic Resolution of sec-Alcohols and Alkyl Mandelates, and Its Kinetic Model
ChemCatChem. 2018. V.10. N12. P.2693-2699. DOI: 10.1002/cctc.201800180 WOS Scopus РИНЦ CAPlusCA OpenAlex
Даты:
| Поступила в редакцию: | 2 февр. 2018 г. |
| Принята к публикации: | 16 мар. 2018 г. |
| Опубликована online: | 23 мар. 2018 г. |
| Опубликована в печати: | 21 июн. 2018 г. |
Идентификаторы БД:
| Web of science: | WOS:000436933700022 |
| Scopus: | 2-s2.0-85048155149 |
| РИНЦ: | 35734693 |
| Chemical Abstracts: | 2018:866688 |
| Chemical Abstracts (print): | 169:51026 |
| OpenAlex: | W2790788071 |