Synthesis of Heptanoic Acid via the Oxidation of Octene-1 by Hydrogen Peroxide under Conditions of Phase-Transfer Catalysis Full article
| Journal |
Catalysis in Industry
ISSN: 2070-0504 , E-ISSN: 2070-0555 |
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| Output data | Year: 2018, Volume: 10, Number: 2, Pages: 105-109 Pages count : 5 DOI: 10.1134/s2070050418020022 | ||
| Tags | carboxylic acids, peroxotungstates, phase-transfer catalysis, quaternary ammonium cations, α-alkenes | ||
| Authors |
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| Affiliations |
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Funding (2)
| 1 | Russian Foundation for Basic Research | 16-03-00127 |
| 2 | Federal Agency for Scientific Organizations | 0303-2016-0008 |
Abstract:
Results from studying the oxidation of octene-1 by a hydrogen peroxide solution to heptanoic acid in a two-phase liquid system under phase-transfer catalysis conditions are presented. Methyl(tri-n-octyl) ammonium tetra(oxodiperoxotungsto)phosphate [MeOct 3 n N]3{PO4[WO(O2)2]4} is used as a catalyst. The conditions of the formation of heptanoic acid with a yield of nearly 90% at temperatures below 100°C and atmospheric pressure in a single stage without organic solvents have been determined. The obtained experimental data provide the possibility to recommend this way for the synthesis of monocarboxylic acids from α-alkenes for the creation of green chemistry processes.
Cite:
Berdnikova P.V.
, Selivanova N.V.
, Oleneva P.V.
, Pai Z.P.
Synthesis of Heptanoic Acid via the Oxidation of Octene-1 by Hydrogen Peroxide under Conditions of Phase-Transfer Catalysis
Catalysis in Industry. 2018. V.10. N2. P.105-109. DOI: 10.1134/s2070050418020022 WOS Scopus РИНЦ OpenAlex
Synthesis of Heptanoic Acid via the Oxidation of Octene-1 by Hydrogen Peroxide under Conditions of Phase-Transfer Catalysis
Catalysis in Industry. 2018. V.10. N2. P.105-109. DOI: 10.1134/s2070050418020022 WOS Scopus РИНЦ OpenAlex
Original:
Бердникова П.В.
, Селиванова Н.В.
, Оленева П.В.
, Пай З.П.
Получение гептановой кислоты окислением октена-1 пероксидом водорода в условиях межфазного катализа
Катализ в промышленности. 2017. Т.17. №6. С.455-459. DOI: 10.18412/1816-0387-2017-6-455-459 РИНЦ AN OpenAlex
Получение гептановой кислоты окислением октена-1 пероксидом водорода в условиях межфазного катализа
Катализ в промышленности. 2017. Т.17. №6. С.455-459. DOI: 10.18412/1816-0387-2017-6-455-459 РИНЦ AN OpenAlex
Dates:
| Submitted: | Nov 13, 2017 |
| Published print: | Apr 1, 2018 |
| Published online: | Jul 5, 2018 |
Identifiers:
| Web of science: | WOS:000437444000003 |
| Scopus: | 2-s2.0-85049679263 |
| Elibrary: | 35757581 |
| OpenAlex: | W2775789166 |